Answer:
Bond energy of carbon-fluorine bond is 485 kJ/mol
Explanation:
Enthalpy change for a reaction, is given as:
![\Delta H_{rxn}=\sum [n_{i}\times (E_{bond})_{i}]-\sum [n_{j}\times (E_{bond})_{j}]](https://tex.z-dn.net/?f=%5CDelta%20H_%7Brxn%7D%3D%5Csum%20%5Bn_%7Bi%7D%5Ctimes%20%28E_%7Bbond%7D%29_%7Bi%7D%5D-%5Csum%20%5Bn_%7Bj%7D%5Ctimes%20%28E_%7Bbond%7D%29_%7Bj%7D%5D)
Where
and
represents average bond energy in breaking "i" th bond and forming "j" th bond respectively.
and
are number of moles of bond break and form respectively.
In this reaction, one mol of C=C, four moles of C-H and one mol of F-F bonds are broken. One mol of C-C bond, four moles of C-H bonds and two moles of C-F bonds are formed
So, 
or, 
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So bond energy of carbon-fluorine bond is 485 kJ/mol
Answer:
1.8 × 10⁻⁴ mol M/s
Explanation:
Step 1: Write the balanced reaction
2 Br⁻ ⇒ Br₂
Step 2: Establish the appropriate molar ratio
The molar ratio of Br⁻ to Br₂ is 2:1.
Step 3: Calculate the rate of appearance of Br₂
The rate of disappearance of Br⁻ at some moment in time was determined to be 3.5 × 10⁻⁴ M/s. The rate of appearance of Br₂ is:
3.5 × 10⁻⁴ mol Br⁻/L.s × (1 mol Br₂/2 mol Br⁻) = 1.8 × 10⁻⁴ mol Br₂/L.s
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