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VARVARA [1.3K]
4 years ago
14

What is the correct order of the 5 para substituents on the carbocation intermediate, if arranged from most stabilizing to least

stabilizing?
CH₃, F, H, OCH₃, NO₂
Chemistry
1 answer:
Bingel [31]4 years ago
8 0

Answer:

CH3, H, NO2, OCH3, F

Explanation:

Alkyl groups have a +I (electrons donation) inductive effect hence they push electrons towards the carbocation centre thereby stabilizing it. On the other hand, with increasing electronegativity and -I (electron withdrawing) inductive effect, the carbocation becomes destabilized. The greatest being F which is very electronegative.

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What technology can make coal a cleaner fuel? fluidized-bed combustion building smoke stacks taller implementing a prewash of co
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3 years ago
Practice Problem: True Stress and Strain A cylindrical specimen of a metal alloy 49.7 mm long and 9.72 mm in diameter is stresse
amm1812

Answer:

The true stress required = 379 MPa

Explanation:

True Stress is the ratio of the internal resistive force to the instantaneous cross-sectional area of the specimen. True Strain is the natural log to the extended length after which load applied to the original length. The cold working stress – strain curve relation is as follows,

σ(t) = K (ε(t))ⁿ, σ(t) is the true stress, ε(t) is the true strain, K is the strength coefficient and n is the strain hardening exponent

True strain is given  by

Epsilon t =㏑ (l/l₀)

Substitute㏑(l/l₀) for ε(t)

σ(t) = K(㏑(l/l₀))ⁿ

Given values l₀ = 49.7mm, l =51.7mm , n =0.2 , σ(t) =379Mpa

379 x 10⁶ = K (㏑(51.7/49.7))^0.2

K = 379 x 10⁶/(㏑(51.7/49.7))^0.2

K = 723.48 MPa

Knowing the constant value would be same as the same material is being used in the second test, we can find out the true stress using the above formula replacing the value of the constant.

σ(t) = K(㏑(l/l₀))ⁿ

l₀ = 49.7mm, l = 51.7mm, n = 0.2, K = 723.48Mpa

σ(t) = 723.48 x 106 x (㏑(51.7/49.7))^0.2

σ(t) = 379 MPa

The true stress necessary to plastically elongate the specimen is 379 MPa.

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