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Allushta [10]
3 years ago
5

g Given that 50.0 mL of 0.100 M magnesium bromide reacts with 13.9 mL of silver nitrate solution according to the unbalanced equ

ation MgBr21aq2 AgNO31aq2 S AgBr1s2 Mg1NO3221aq2 (a) What is the molarity of the AgNO3 solution
Chemistry
1 answer:
ipn [44]3 years ago
3 0

Answer:

0.719M AgNO₃

Explanation:

Based on the reaction:

MgBr₂ + 2AgNO₃ ⇄ 2AgBr + Mg(NO₃)₂

<em>1 mole of magnesium bromide reacts completely with 2 moles of AgNO₃</em>

<em />

To find molarity of AgNO₃ solution we need to determine moles of AgNO₃ and, as molarity is the ratio of moles over liter (13.9mL = 0.0139L). Now, to determine moles of AgNO₃ we need to use the reaction, thus:

<em>Moles AgNO₃:</em>

<em />

Moles of MgBr₂ are:

50.0mL = 0.050L * (0.100mol / L) = 0.00500 moles of MgBr₂.

As the silver nitrate reacts completely and 2 moles of AgNO₃ reacts per mole of MgBr₂:

0.00500 moles MgBr₂ * (2 moles AgNO₃ / 1 mole MgBr₂) =

0.0100 moles of AgNO₃ are in the solution.

And molarity is:

0.0100 moles AgNO₃ / 0.0139L =

<h3>0.719M AgNO₃</h3>
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he rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy . If the rate c
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The question is incomplete, here is the complete question:

The rate constant of a certain reaction is known to obey the Arrhenius equation, and to have an activation energy Ea = 71.0 kJ/mol . If the rate constant of this reaction is 6.7 M^(-1)*s^(-1) at 244.0 degrees Celsius, what will the rate constant be at 324.0 degrees Celsius?

<u>Answer:</u> The rate constant at 324°C is 61.29M^{-1}s^{-1}

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To calculate rate constant at two different temperatures of the reaction, we use Arrhenius equation, which is:

\ln(\frac{K_{324^oC}}{K_{244^oC}})=\frac{E_a}{R}[\frac{1}{T_1}-\frac{1}{T_2}]

where,

K_{244^oC} = equilibrium constant at 244°C = 6.7M^{-1}s^{-1}

K_{324^oC} = equilibrium constant at 324°C = ?

E_a = Activation energy = 71.0 kJ/mol = 71000 J/mol   (Conversion factor:  1 kJ = 1000 J)

R = Gas constant = 8.314 J/mol K

T_1 = initial temperature = 244^oC=[273+244]K=517K

T_2 = final temperature = 324^oC=[273+324]K=597K

Putting values in above equation, we get:

\ln(\frac{K_{324^oC}}{6.7})=\frac{71000J}{8.314J/mol.K}[\frac{1}{517}-\frac{1}{597}]\\\\K_{324^oC}=61.29M^{-1}s^{-1}

Hence, the rate constant at 324°C is 61.29M^{-1}s^{-1}

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