B, Rocks are always being recycled into different forms.
Answer:
hydrogen atom and oxygen atom
Answer:
KOH contains only one K, so a mole of KOH contains one mole of K. How many atoms of K are in 1 mole of KOH? There are 6.022 × 1023 atoms of potassium in every mole of potassium. Since one mole of KOH contains one mole of K, the answer is 6.022×1023 atoms of K.
Explanation:
because it a essential for good heat transfer
Answer:
b. Second order in NO and first order in O₂.
Explanation:
A. The mechanism
![\rm 2NO\xrightarrow[k_{-1}]{k_{1}}N_{2}O_{2} \, (fast)\\\rm N_{2}O_{2} + O_{2}\xrightarrow{k_{2}} 2NO_{2} \, (slow)](https://tex.z-dn.net/?f=%5Crm%202NO%5Cxrightarrow%5Bk_%7B-1%7D%5D%7Bk_%7B1%7D%7DN_%7B2%7DO_%7B2%7D%20%5C%2C%20%28fast%29%5C%5C%5Crm%20N_%7B2%7DO_%7B2%7D%20%2B%20O_%7B2%7D%5Cxrightarrow%7Bk_%7B2%7D%7D%202NO_%7B2%7D%20%5C%2C%20%28slow%29)
B. The rate expressions
![-\dfrac{\text{d[NO]} }{\text{d}t} = k_{1}[\text{NO]}^{2} - k_{-1} [\text{N}_{2}\text{O}_{2}]^{2}\\\\\rm -\dfrac{\text{d[N$_{2}$O$_{2}$]}}{\text{d}t} = -\dfrac{\text{d[O$_{2}$]}}{\text{d}t} = k_{2}[ N_{2}O_{2}][O_{2}] - k_{1} [NO]^{2}\\\\\dfrac{\text{d[NO$_{2}$]}}{\text{d}t}= k_{2}[ N_{2}O_{2}][O_{2}]](https://tex.z-dn.net/?f=-%5Cdfrac%7B%5Ctext%7Bd%5BNO%5D%7D%20%7D%7B%5Ctext%7Bd%7Dt%7D%20%3D%20k_%7B1%7D%5B%5Ctext%7BNO%5D%7D%5E%7B2%7D%20-%20k_%7B-1%7D%20%5B%5Ctext%7BN%7D_%7B2%7D%5Ctext%7BO%7D_%7B2%7D%5D%5E%7B2%7D%5C%5C%5C%5C%5Crm%20-%5Cdfrac%7B%5Ctext%7Bd%5BN%24_%7B2%7D%24O%24_%7B2%7D%24%5D%7D%7D%7B%5Ctext%7Bd%7Dt%7D%20%3D%20-%5Cdfrac%7B%5Ctext%7Bd%5BO%24_%7B2%7D%24%5D%7D%7D%7B%5Ctext%7Bd%7Dt%7D%20%3D%20k_%7B2%7D%5B%20N_%7B2%7DO_%7B2%7D%5D%5BO_%7B2%7D%5D%20-%20k_%7B1%7D%20%5BNO%5D%5E%7B2%7D%5C%5C%5C%5C%5Cdfrac%7B%5Ctext%7Bd%5BNO%24_%7B2%7D%24%5D%7D%7D%7B%5Ctext%7Bd%7Dt%7D%3D%20k_%7B2%7D%5B%20N_%7B2%7DO_%7B2%7D%5D%5BO_%7B2%7D%5D)
The last expression is the rate law for the slow step. However, it contains the intermediate N₂O₂, so it can't be the final answer.
C. Assume the first step is an equilibrium
If the first step is an equilibrium, the rates of the forward and reverse reactions are equal. The equilibrium is only slightly perturbed by the slow leaking away of N₂O₂ to form product.
![\rm k_{1}[NO]^{2} = k_{-1} [N_{2}O_{2}]\\\\\rm [N_{2}O_{2}] = \dfrac{k_{1}}{k_{-1}}[NO]^{2}](https://tex.z-dn.net/?f=%5Crm%20k_%7B1%7D%5BNO%5D%5E%7B2%7D%20%3D%20k_%7B-1%7D%20%5BN_%7B2%7DO_%7B2%7D%5D%5C%5C%5C%5C%5Crm%20%5BN_%7B2%7DO_%7B2%7D%5D%20%3D%20%5Cdfrac%7Bk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D)
D. Substitute this concentration into the rate law
![\rm \dfrac{\text{d[NO$_{2}$]}}{\text{d}t}= \dfrac{k_{2}k_{1}}{k_{-1}}[NO]^{2} [O_{2}] = k[NO]^{2} [O_{2}]](https://tex.z-dn.net/?f=%5Crm%20%5Cdfrac%7B%5Ctext%7Bd%5BNO%24_%7B2%7D%24%5D%7D%7D%7B%5Ctext%7Bd%7Dt%7D%3D%20%5Cdfrac%7Bk_%7B2%7Dk_%7B1%7D%7D%7Bk_%7B-1%7D%7D%5BNO%5D%5E%7B2%7D%20%5BO_%7B2%7D%5D%20%3D%20k%5BNO%5D%5E%7B2%7D%20%5BO_%7B2%7D%5D)
The reaction is second order in NO and first order in O₂.