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3 years ago

Nitrogen monoxide, NO, reacts with hydrogen, H₂, according to the following equation.

Chemistry

1 answer:

Anvisha [2.4K]3 years ago

8 0

Answer : The rate law for the overall reaction is, $Rate=k[NO]^2[H_2]$

Explanation :

Rate law : It is defined as the expression which expresses the rate of the reaction in terms of molar concentration of the reactants with each term raised to the power their stoichiometric coefficient of that reactant in the balanced chemical equation.

As we are given the mechanism for the reaction :

Step 1 : $2NO+H_2\rightarrow N_2+H_2O_2$ (slow)

Step 2 : $H_2O_2+H_2\rightarrow 2H_2O$ (fast)

Overall reaction : $2NO+2H_2\rightarrow N_2+2H_2O$

The rate law expression for overall reaction should be in terms of $NO\text{ and }H_2$ .

As we know that the slow step is the rate determining step. So,

The slow step reaction is,

$2NO+H_2\rightarrow N_2+H_2O_2$

The expression of rate law for this reaction will be,

$Rate=k[NO]^2[H_2]$

Hence, the rate law for the overall reaction is, $Rate=k[NO]^2[H_2]$

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The reaction na 3po 4( aq) 3 agno3( aq) → ag 3po 4( s) 3 nano 3( aq) is best classified as a(n):_____.

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The reaction $Na_{3} PO_{4} ( aq) +3AgNO_{3} (aq)$ → $Ag_{3} PO_{4} ( aq) +3NaNO_{3} (aq)$ is best classified as double displacement reaction.

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1 year ago

A sample was prepared by mixing 18. ml of 3.00 x 10^-3 m crystal violet (cv) with 2.00 ml of 0.250 m naoh. calculate the resulti

Aleks [24]

Answer : The resulting concentrations of CV and NaOH are 0.0027 M and 0.025 M respectively.

Explanation :

Step 1 : Find moles of crystal violet and NaOH.

The molarity formula is

$Molarity = \frac{mol}{L}$

Molarity of crystal violet = $3.00 \times 10^{-3} = \frac{mol (CrystalViolet)}{L}$

The volume of crystal violet solution is 18 mL which is 0.018 L.

Moles of crystal violet = $3.00 \times 10^{-3} \times 0.018 = 5.4 \times 10^{-5}$

Moles of crystal violet = 5.4 x 10⁻⁵

Moles of NaOH = $Molarity \times L = 0.250 \times 0.00200 = 5.00 \times 10^{-4}$

Moles of NaOH = 5.00 x 10⁻⁴

Step 2 : Find total volume of the solution

The total volume of the solution after mixing NaOH and crystal violet is

0.018 L + 0.00200 = 0.020 L

Step 3 : Use molarity formula to find final concentrations

Molarity of crystal violet = $\frac{mol(CrystalViolet)}{Total Volume(L) } = \frac{5.4 \times 10^{-5}}{0.020} = 2.7 \times 10^{-3}$

Final concentration of CV = 0.0027 M

Molarity of NaOH= $\frac{mol(NaOH)}{Total Volume(L) } = \frac{5.00 \times 10^{-4}}{0.020} = 0.025 \times 10^{-3}$

NaOH is a strong base and dissociates completely as follows.

$NaOH (aq) \rightarrow Na^{+} (aq) + OH^{-} (aq)$

The mole ratio of NaOH and OH⁻ is 1:1 . Therefore the concentration of OH⁻ is same as that of NaOH.

Concentration of OH⁻ = 0.025 M

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Consider this initial-rate data at a certain temperature for the reaction described by N2O3(

Yuliya22 [10]

N2O3(g)→NO(g)+NO2(g)

[N2O3] Initial Rate
0.1 M r(t)=0.66 M/s
0.2 M r(t)=1.32 M/s
0.3 M r(t)=1.98 M/s

We can have the relationship:

([N2O3]/[N2O3]0)^m=r(t)/r0(t)
However,
([N2O3]/[N2O3]0) = 2

Also, we assume m=1 which is the order of the reaction.

Thus, the relationship is simplified to,

r(t)/r0(t) = 2

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