<span><span>N2</span><span>O3</span><span>(g)</span>→NO<span>(g)</span>+<span>NO2</span><span>(g)</span></span>
<span><span>[<span>N2</span><span>O3</span>]</span> Initial Rate</span>
<span>0.1 M r<span>(t)</span>=0.66</span> M/s
<span>0.2 M r<span>(t)</span>=1.32</span> M/s
<span>0.3 M r<span>(t)</span>=1.98</span> M/s
We can have the relationship:
<span>(<span><span>[<span>N2</span><span>O3</span>]/</span><span><span>[<span>N2</span><span>O3</span>]</span>0</span></span>)^m</span>=<span><span>r<span>(t)/</span></span><span><span>r0</span><span>(t)
However,
</span></span></span>([N2O3]/[N2O3]0) = 2
Also, we assume m=1 which is the order of the reaction.
Thus, the relationship is simplified to,
r(t)/r0(t) = 2
r<span>(t)</span>=k<span>[<span>N2</span><span>O3</span>]</span>
0.66 <span>M/s=k×0.1 M</span>
<span>k=6.6</span> <span>s<span>−<span>1</span></span></span>
Answer:
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Explanation:
Mass of KCl= 1.08 g
<h3>Further explanation</h3>
Given
1 g of K₂CO₃
Required
Mass of KCl
Solution
Reaction
K₂CO₃ +2HCl ⇒ 2KCl +H₂O + CO₂
mol of K₂CO₃(MW=138 g/mol) :
= 1 g : 138 g/mol
= 0.00725
From the equation, mol ratio K₂CO₃ : KCl = 1 : 2, so mol KCl :
= 2/1 x mol K₂CO₃
= 2/1 x 0.00725
= 0.0145
Mass of KCl(MW=74.5 g/mol) :
= mol x MW
= 0.0145 x 74.5
= 1.08 g
