Answer:
Be
Explanation:
Reactivity increases from left to right and decreases from the top of the column to the bottom of column
Answer:but-1-ene
Explanation:This is an E2 elimination reaction .
Kindly refer the attachment for complete reaction and products.
Sodium tert-butoxide is a bulky base and hence cannot approach the substrate 2-chlorobutane from the more substituted end and hence major product formed here would not be following zaitsev rule of elimination reaction.
Sodium tert-butoxide would approach from the less hindered side that is through the primary centre and hence would lead to the formation of 1-butene .The major product formed in this reaction would be 1-butene .
As the mechanism of the reaction is E-2 so it will be a concerted mechanism and as sodium tert-butoxide will start abstracting the primary hydrogen through the less hindered side simultaneously chlorine will start leaving. As the steric repulsion in this case is less hence the transition state is relatively stabilised and leads to the formation of a kinetic product 1-butene.
Kinetic product are formed when reactions are dependent upon rate and not on thermodynamical stability.
2-butene is more thermodynamically6 stable as compared to 1-butene
The major product formed does not follow the zaitsev rule of forming a more substituted alkene as sodium tert-butoxide cannot approach to abstract the secondary proton due to steric hindrance.
Answer:
C₂Cl₄
Explanation:
To know if free rotation around a bond in a compound is possible, we need to see the structure of the compound (picture in attachment).
In single bonds, which are formed by σ bonds, the atoms are not fixed in a single position, and free rotation is permitted.
Double and triple bonds are formed by a σ bond and one or two π bonds, respectively. These bonds do not allow rotation, since it is not possible to twist the ends without breaking the π bond.
The chloroethylene (C₂Cl₄) has two carbons with an sp2-sp2 hybridization, they are bonded together by a double bond. <u>Free rotation on this bond is not possible, because six atoms, including the carbon atoms, doubly bonded and the four chlorine atoms bonded to them, must be on the same plane. </u>
Answer: 1.56 ATM
Explanation: if we assume temperature is constant, gas obeys
Boyles law pV= constant. Then p1·V1= p2·V2. And V1 = p2V2/p1
= 3.0 atm·0,52 l / 1.0 atm