Answer:
11.31g NaClO₂
Explanation:
<em> Is given 250mL of a 1.60M chlorous acid HClO2 solution. Ka is 1.110x10⁻². What mass of NaClO₂ should the student dissolve in the HClO2 solution to turn it into a buffer with pH =1.45? </em>
It is possible to answer this question using Henderson-Hasselbalch equation:
pH = pKa + log₁₀ [A⁻] / [HA]
<em>Where pKa is -log Ka = 1.9547; [A⁻] is the concentration of the conjugate base (NaClO₂), [HA] the concentration of the weak acid</em>
You can change the concentration of the substance if you write the moles of the substances:
[Moles HClO₂] = 250mL = 0.25L×(1.60mol /L) = <em>0.40 moles HClO₂</em>
Replacing in H-H expression, as the pH you want is 1.45:
1.45 = 1.9547 + log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]
-0.5047 = log₁₀ [Moles NaClO₂] / [0.40 moles HClO₂]
<em>0.3128 = </em>[Moles NaClO₂] / [0.40 moles HClO₂]
0.1251 = Moles NaClO₂
As molar mass of NaClO₂ is 90.44g/mol, mass of 0.1251 moles of NaClO₂ is:
0.1251 moles NaClO₂ ₓ (90.44g / mol) =
<h3>11.31g NaClO₂</h3>
This reaction is called silioconic
Answer:
A, C and D are correct.
Explanation:
Hello.
In this case, since the relationship between the vapor pressure of a solution is directly proportional to the mole fraction of the solvent and the vapor pressure of the pure solvent as stated by the Raoult's law:
Since the solute is not volatile, the mole fraction of the solute is not taken into account for vapor pressure of the solution, therefore A is correct whereas B is incorrect.
Moreover, since the higher the vapor pressure, the weaker the intermolecular forces due to the fact that less more molecules are like to change from liquid to vapor and therefore more energy is required for such change, we can evidence that both C and D are correct.
Best regards.
