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3 years ago

What is the reaction scheme for the experiment of synthesis of methyl salicylate

Chemistry

1 answer:

soldier1979 [14.2K]3 years ago

3 0

The methyl salicylate (wintergreen oil) is the methyl ester of salicylic acid.

Methyl salicylate is produced by esterifying salicylic acid with methanol, the reaction scheme is attached to this answer. In the past, it was commonly distilled from the twigs of Betula lenta (sweet birch) and Gaultheria procumbens (eastern teaberry or wintergreen).

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3 years ago

Calculate the activity coefficients for the following conditions:

uysha [10]

Answer:

For a: The activity coefficient of copper ions is 0.676

For b: The activity coefficient of potassium ions is 0.851

For c: The activity coefficient of potassium ions is 0.794

Explanation:

To calculate the activity coefficient of an ion, we use the equation given by Debye and Huckel, which is:

$-\log\gamma_i=\frac{0.51\times Z_i^2\times \sqrt{\mu}}{1+(3.3\times \alpha _i\times \sqrt{\mu})}$ ........(1)

where,

$\gamma_i$ = activity coefficient of ion

$Z_i$ = charge of the ion

$\mu$ = ionic strength of solution

$\alpha _i$ = diameter of the ion in nm

To calculate the ionic strength, we use the equation:

$\mu=\frac{1}{2}\sum_{i=1}^n(C_iZ_i^2)$ ......(2)

where,

$C_i$ = concentration of i-th ions

$Z_i$ = charge of i-th ions

For a:

We are given:

0.01 M NaCl solution:

Calculating the ionic strength by using equation 2:

$C_{Na^+}=0.01M\\Z_{Na^+}=+1\\C_{Cl^-}=0.01M\\Z_{Cl^-}=-1$

Putting values in equation 2, we get:

$\mu=\frac{1}{2}[(0.01\times (+1)^2)+(0.01\times (-1)^2)]\\\\\mu=0.01M$

Now, calculating the activity coefficient of $Cu^{2+}$ ion in the solution by using equation 1:

$Z_{Cu^{2+}}=2+\\\alpha_{Cu^{2+}}=0.6\text{ (known)}\\\mu=0.01M$

Putting values in equation 1, we get:

$-\log\gamma_{Cu^{2+}}=\frac{0.51\times (+2)^2\times \sqrt{0.01}}{1+(3.3\times 0.6\times \sqrt{0.01})}\\\\-\log\gamma_{Cu^{2+}}=0.17\\\\\gamma_{Cu^{2+}}=10^{-0.17}\\\\\gamma_{Cu^{2+}}=0.676$

Hence, the activity coefficient of copper ions is 0.676

For b:

We are given:

0.025 M HCl solution:

Calculating the ionic strength by using equation 2:

$C_{H^+}=0.025M\\Z_{H^+}=+1\\C_{Cl^-}=0.025M\\Z_{Cl^-}=-1$

Putting values in equation 2, we get:

$\mu=\frac{1}{2}[(0.025\times (+1)^2)+(0.025\times (-1)^2)]\\\\\mu=0.025M$

Now, calculating the activity coefficient of $K^{+}$ ion in the solution by using equation 1:

$Z_{K^{+}}=+1\\\alpha_{K^{+}}=0.3\text{ (known)}\\\mu=0.025M$

Putting values in equation 1, we get:

$-\log\gamma_{K^{+}}=\frac{0.51\times (+1)^2\times \sqrt{0.025}}{1+(3.3\times 0.3\times \sqrt{0.025})}\\\\-\log\gamma_{K^{+}}=0.070\\\\\gamma_{K^{+}}=10^{-0.070}\\\\\gamma_{K^{+}}=0.851$

Hence, the activity coefficient of potassium ions is 0.851

For c:

We are given:

0.02 M $K_2SO_4$ solution:

Calculating the ionic strength by using equation 2:

$C_{K^+}=(2\times 0.02)=0.04M\\Z_{K^+}=+1\\C_{SO_4^{2-}}=0.02M\\Z_{SO_4^{2-}}=-2$

Putting values in equation 2, we get:

$\mu=\frac{1}{2}[(0.04\times (+1)^2)+(0.02\times (-2)^2)]\\\\\mu=0.06M$

Now, calculating the activity coefficient of $K^{+}$ ion in the solution by using equation 1:

$Z_{K^{+}}=+1\\\alpha_{K^{+}}=0.3\text{ (known)}\\\mu=0.06M$

Putting values in equation 1, we get:

$-\log\gamma_{K^{+}}=\frac{0.51\times (+1)^2\times \sqrt{0.06}}{1+(3.3\times 0.3\times \sqrt{0.06})}\\\\-\log\gamma_{K^{+}}=0.1\\\\\gamma_{K^{+}}=10^{-0.1}\\\\\gamma_{K^{+}}=0.794$

Hence, the activity coefficient of potassium ions is 0.794

6 0

3 years ago