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Scilla [17]
3 years ago
13

The most common element in the atmosphere are

Chemistry
1 answer:
Ivanshal [37]3 years ago
8 0
Nitrogen and oxygen are the most prevalent in the atmosphere.
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3 years ago
Consider the following reaction: CO2(g)+CCl4(g)⇌2COCl2(g) Calculate ΔG for this reaction at25 ∘C under these conditions: PCO2PCC
Salsk061 [2.6K]

<u>Answer:</u> The \Delta G for the reaction is 54.6 kJ/mol

<u>Explanation:</u>

For the given balanced chemical equation:

CO_2(g)+CCl_4(g)\rightleftharpoons 2COCl_2(g)

We are given:

\Delta G^o_f_{CO_2}=-394.4kJ/mol\\\Delta G^o_f_{CCl_4}=-62.3kJ/mol\\\Delta G^o_f_{COCl_2}=-204.9kJ/mol

  • To calculate \Delta G^o_{rxn} for the reaction, we use the equation:

\Delta G^o_{rxn}=\sum [n\times \Delta G_f(product)]-\sum [n\times \Delta G_f(reactant)]

For the given equation:

\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(COCl_2)})]-[(1\times \Delta G^o_f_{(CO_2)})+(1\times \Delta G^o_f_{(CCl_4)})]

Putting values in above equation, we get:

\Delta G^o_{rxn}=[(2\times (-204.9))-((1\times (-394.4))+(1\times (-62.3)))]\\\Delta G^o_{rxn}=46.9kJ=46900J

Conversion factor used = 1 kJ = 1000 J

  • The expression of K_p for the given reaction:

K_p=\frac{(p_{COCl_2})^2}{p_{CO_2}\times p_{CCl_4}}

We are given:

p_{COCl_2}=0.760atm\\p_{CO_2}=0.140atm\\p_{CCl_4}=0.180atm

Putting values in above equation, we get:

K_p=\frac{(0.760)^2}{0.140\times 0.180}\\\\K_p=22.92

  • To calculate the Gibbs free energy of the reaction, we use the equation:

\Delta G=\Delta G^o+RT\ln K_p

where,

\Delta G = Gibbs' free energy of the reaction = ?

\Delta G^o = Standard gibbs' free energy change of the reaction = 46900 J

R = Gas constant = 8.314J/K mol

T = Temperature = 25^oC=[25+273]K=298K

K_p = equilibrium constant in terms of partial pressure = 22.92

Putting values in above equation, we get:

\Delta G=46900J+(8.314J/K.mol\times 298K\times \ln(22.92))\\\\\Delta G=54659.78J/mol=54.6kJ/mol

Hence, the \Delta G for the reaction is 54.6 kJ/mol

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3 years ago
How many moles in 32.7 grams of water vapor?
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To find moles from grams divide the number of moles by the molar mass...

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6 0
3 years ago
Read 2 more answers
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