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bija089 [108]
3 years ago
14

6. A 0.1310 g sample of an unknown diprotic acid is diluted to 100.00 mL and titrated by using 0.1910 M NaOH. If 14.20 mL of the

NaOH solution is required to reach the second equivalence point, what is the molar mass of the acid?
Chemistry
1 answer:
miskamm [114]3 years ago
3 0

Answer:

MM_{acid}=96.9g/mol

Explanation:

Hello,

In this case, it is more convenient to define this titration in terms of normality:

eq-g_{acid}=eq-g_{NaOH}\\N_{acid}V_{acid}=N_{NaOH}V_{NaOH}

In such a way, the normality of the acid, considering the normality of sodium hydroxide equals its molarity (one hydroxile in its structure) is:

N_{acid}=\frac{N_{NaOH}V_{NaOH}}{V_{acid}}=\frac{0.1910N*14.20mL}{100.00mL} \\N_{acid}=0.0271\frac{eq-g}{L}

Thus, the moles are:

n_{acid}=0.0271\frac{eq-g}{L}*0.10000L*\frac{1mol}{2eq-g} =1.356x10^{-3}mol

Hence, the molar mass:

MM_{acid}=\frac{0.1310g}{1.356x10^{-3}mol} \\MM_{acid}=96.9g/mol

Best regards.

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Cloud [144]

Answer:

the equilibrium concentration of [PCl₅] is 3.64*10⁻³ M

Explanation:

for the reaction

PCl₅(g) → PCl₃(g) + Cl₂(g)

where

Kc= [PCl₃]*[Cl₂]/[PCl₅] = 2.0*10¹ M = 20 M

and [A] denote concentrations of A

if initially the mixture is pure PCl₅ , then it will dissociate according to the reaction and since always one mole of PCl₃(g) is generated with one mole of Cl₂(g) , the total number of moles of both at the end is the same → they have the same concentration → [PCl₃(g)] = [Cl₂]=0.27 M

therefore

Kc= [PCl₃]*[Cl₂]/[PCl₅] = 0.27 M* 0.27 M /[PCl₅] = 20 M

[PCl₅]  =  0.27 M* 0.27 M / 20 M = 3.64*10⁻³ M

[PCl₅]  = 3.64*10⁻³ M

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6 0
3 years ago
a piece of food is burned in a calorimeter that contains 200.0g of water. If the temperature of the water rose from 65.0°C to 83
Flauer [41]

Answer: 15062.4 Joules

Explanation:

The quantity of heat energy (Q) required to heat a substance depends on its Mass (M), specific heat capacity (C) and change in temperature (Φ)

Thus, Q = MCΦ

Since,

Q = ?

Mass of food = 200.0g

C = 4.184 j/g°C

Φ = (Final temperature - Initial temperature)

= 83.0°C - 65.0°C = 18°C

Then, Q = MCΦ

Q = 200.0g x 4.184 j/g°C x 18°C

Q = 15062.4 J

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What minimum energy is required to excite a vibration in HF?
Elodia [21]

Answer:

The energy of a vibrating molecule is quantized much like the energy of an electron in the hydrogen atom. The energy levels of a vibrating molecule are given by the equation: En=(n+21)hv where n is a quantum number with possible values of 1, 2, ... and v is the frequency of vibration.

Explanation:

hope it helps.

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7 0
3 years ago
Consider the reaction: CaCO3(s) à CaO(s) + CO2(g)
Vsevolod [243]

Answer:

131.5 kJ

Explanation:

Let's consider the following reaction.

CaCO₃(s) → CaO(s) + CO₂(g)

First, we will calculate the standard enthalpy of the reaction (ΔH°).

ΔH° = 1 mol × ΔH°f(CaO(s)) + 1 mol × ΔH°f(CO₂(g) ) - 1 mol × ΔH°f(CaCO₃(s) )

ΔH° = 1 mol × (-634.9 kJ/mol) + 1 mol × (-393.5 kJ/mol) - 1 mol × (-1207.6 kJ/mol)

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Then, we calculate the standard entropy of the reaction (ΔS°).

ΔS° = 1 mol × S°(CaO(s)) + 1 mol × S°(CO₂(g) ) - 1 mol × S°(CaCO₃(s) )

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ΔS° = 160.2 J/K = 0.1602 kJ/K

Finally, we calculate the standard Gibbs free energy of the reaction at T = 25°C = 298 K.

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ΔG° = 131.5 kJ

6 0
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kap26 [50]

Answer:

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Explanation:

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8 0
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