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bija089 [108]
3 years ago
14

6. A 0.1310 g sample of an unknown diprotic acid is diluted to 100.00 mL and titrated by using 0.1910 M NaOH. If 14.20 mL of the

NaOH solution is required to reach the second equivalence point, what is the molar mass of the acid?
Chemistry
1 answer:
miskamm [114]3 years ago
3 0

Answer:

MM_{acid}=96.9g/mol

Explanation:

Hello,

In this case, it is more convenient to define this titration in terms of normality:

eq-g_{acid}=eq-g_{NaOH}\\N_{acid}V_{acid}=N_{NaOH}V_{NaOH}

In such a way, the normality of the acid, considering the normality of sodium hydroxide equals its molarity (one hydroxile in its structure) is:

N_{acid}=\frac{N_{NaOH}V_{NaOH}}{V_{acid}}=\frac{0.1910N*14.20mL}{100.00mL} \\N_{acid}=0.0271\frac{eq-g}{L}

Thus, the moles are:

n_{acid}=0.0271\frac{eq-g}{L}*0.10000L*\frac{1mol}{2eq-g} =1.356x10^{-3}mol

Hence, the molar mass:

MM_{acid}=\frac{0.1310g}{1.356x10^{-3}mol} \\MM_{acid}=96.9g/mol

Best regards.

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