Arrange these elements in order of decreasing atomic size:sulfur, chlorine, aluminium, and sodium.

Anna [14]

Considering the Hess's Law, the enthalpy change for the reaction is 221.8 kJ/mol.

Hess's Law indicates that the enthalpy change in a chemical reaction will be the same whether it occurs in a single stage or in several stages. That is, the sum of the ∆H of each stage of the reaction will give us a value equal to the ∆H of the reaction when it occurs in a single stage.

In this case you want to calculate the enthalpy change of:

C₂H₄ (g) + 6 F₂ (g) → 2 CF₄ (g) + 4 HF (g)

which occurs in three stages.

You know the following reactions, with their corresponding enthalpies:

Equation 1: H₂ (g) + F₂ (g) → 2 HF (g) ∆H° = -79.2 kJ/mol

Equation 2: C (s) + 2 F₂ (g) → CF₄ (g) ∆H° = 141.3 kJ/mol

Equation 3: 2 C(s) + 2 H₂ (g) → C₂H₄ (g) ∆H° = -97.6 kJ/mol

Because of the way formation reactions are defined, any chemical reaction can be written as a combination of formation reactions, some going forward and some going back.

<h3 /><h3>FIRST STEP</h3>

First, to obtain the enthalpy of the desired chemical reaction you need one mole of C₂H₄ (g) on reactant side and it is present in first equation. Since this equation has one mole of C₂H₄ (g) on the product side, it is necessary to locate it on the reactant side (invert it).

When an equation is inverted, the sign of ΔH° also changes.

<h3>SECOND STEP</h3>

Now, you need 2 moles of CF₄ (g) on the product side. The second equation has 1 mole of CF₄ (g) on the product side, so it is necessary to multiply it by 2 to obtain 2 moles of CF₄ (g).

Since enthalpy is an extensive property, that is, it depends on the amount of matter present, since the equation is multiply by 2, the variation of enthalpy also.

<h3>THIRD STEP</h3>

Finally, you need 4 moles of HF (g) on the product side. The first equation has 2 moles of HF (g) on the product side, so it is necessary to multiply it by 2 to obtain 4 moles of the compound.

Since the equation is multiply by 2, the variation of enthalpy also is multiplied by 2.

<h3>SUMMARY</h3>

In summary, you know that three equations with their corresponding enthalpies are:

Equation 1: 2 H₂ (g) + 2 F₂ (g) → 4 HF (g) ∆H° = -158.4 kJ/mol

Equation 2: 2 C (s) + 4 F₂ (g) → 2 CF₄ (g) ∆H° = 282.6 kJ/mol

Equation 3: C₂H₄ (g) → 2 C(s) + 2 H₂ (g) ∆H° = 97.6 kJ/mol

Adding or canceling the reactants and products as appropriate, and adding the enthalpies algebraically, you obtain:

C₂H₄ (g) + 6 F₂ (g) → 2 CF₄ (g) + 4 HF (g) ΔH°= 221.8 kJ/mol

Finally, the enthalpy change for the reaction is 221.8 kJ/mol.

Learn more about molar enthalpy:

7 0

2 years ago

Calculate ΔrG∘ at 298 K for the following reactions.CO(g)+H2O(g)→H2(g)+CO2(g)2-Predict the effect on ΔrG∘ of lowering the temper

KonstantinChe [14]

Answer:

1) ΔG°r(298 K) = - 28.619 KJ/mol

2) ΔG°r will decrease with decreasing temperature

Explanation:

CO(g) + H2O(g) → H2(g) + CO2(g)

1) ΔG°r = ∑νiΔG°f,i

⇒ ΔG°r(298 K) = ΔG°CO2(g) + ΔG°H2(g) - ΔG°H2O(g) - ΔG°CO(g)

from literature, T = 298 K:

∴ ΔG°CO2(g) = - 394.359 KJ/mol

∴ ΔG°CO(g) = - 137.152 KJ/mol

∴ ΔG°H2(g) = 0 KJ/mol........pure substance

∴ ΔG°H2O(g) = - 228.588 KJ/mol

⇒ ΔG°r(298 K) = - 394.359 KJ/mol + 0 KJ/mol - ( - 228.588 KJ/mol ) - ( - 137.152 KJ7mol )

⇒ ΔG°r(298 K) = - 28.619 KJ/mol

2) K = e∧(-ΔG°/RT)

∴ R = 8.314 E-3 KJ/K.mol

∴ T = 298 K

⇒ K = e∧(-28.619/(8.314 E-3)(298) = 9.624 E-6

⇒ ΔG°r = - RTLnK

If T (↓) ⇒ ΔG°r (↓)

assuming T = 200 K

⇒ ΔG°r(200 K) = - (8.314 E-3)(200)Ln(9.624E-3)

⇒ ΔG°r (200K) = - 19.207 KJ/mol < ΔG°r(298 K) = - 28.619 KJ/mol

6 0

3 years ago

Luke and Sian want to plant a vegetable garden in their yard. A soil testing kit measures the soil pH at 5.0, but the lettuce th

dexar [7]

Answer:

So, Luke and Sian has to increase the pH of the soil by adding base to it.

Explanation:

The pH is defined as the negative logarithm of the hydrogen ion concentration in their aqueous solution.

$pH=-\log[H^+]$

With increase in hydrogen ion concentration the pH value decreases.
With decrease in hydrogen ion concentration the pH value increases.

The pH of the soil after testing it on a kit comes out be 5.0, but they both need pH of the soil to 6.5.

Comparison of pH of soil:

= 5.0 < 6.5

= High hydrogen ion concentration > High hydrogen ion concentration

So, Luke and Sian has to increase the pH of the soil by adding base .Doing so will decrease the hydrogen ion concentration in the soil (where as addition of acid lower the pH of soil).

4 0

3 years ago

Please dont answer if you dont know.<br>It's the parts of a wave

Marina86 [1]

Answer:

1) wavelength
2) trough
3) amplitude
4) crest

Explanation:

Hope this helps!

5 0

3 years ago

How do you use the changes in the phase of water to keep you cool?

sineoko [7]

Answer:

by freezing

Explanation:

8 0

3 years ago

Arrange these elements in order of decreasing atomic size:sulfur, chlorine, aluminium, and sodium.​

Arrange these elements in order of decreasing atomic size:sulfur, chlorine, aluminium, and sodium.