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natima [27]
3 years ago
5

Automotive air bags inflate when sodium azide, NaN3, rapidly decomposes to its component elements: 2NaN3(s)→2Na(s)+3N2(g)

Chemistry
1 answer:
Brums [2.3K]3 years ago
8 0

Answer:

\boxed{\text{(a) 2.85 mol; (b) 21.7 g; (c) 712 g}}

Explanation:

We will need a balanced chemical equation with molar masses, volumes, and concentrations, so, let's gather all the information in one place.

M_r:     65.01                         28.01

         2NaN₃(s) ⟶ 2Na(s) + 3N₂(g)

n/mol:   1.90

m/g:                                        14.0

(a) Moles of N₂

The molar ratio is 3 mol N₂ = 2 mol NaN₃

\text{Moles of N}_{2} = \text{1.90 mol NaN$_{3}$}\times \dfrac{\text{3 mol N}_{2}}{\text{2 mol NaN$_{3}$}}= \textbf{2.85 mol N}_{2}\\\\\text{The reaction produces $\boxed{\textbf{2.85 mol N}_{2}}$}

(b) Mass of NaN₃

(i) Moles of N₂

\text{Moles of N}_{2} = \text{14.0 g N}_{2} \times \dfrac{\text{1 mol N}_{2}}{\text{ 28.01 g N}_{2}} = \text{0.4998 mol N}_{2}

(ii) Moles of NaN₃

\text{Moles of NaN}_{3} =\text{0.4998 mol N}_{2} \times \dfrac{\text{2 mol NaN}_{3}}{\text{3 mol N}_{2}} = \text{0.3332 mol NaN}_{3}

(iii) Mass of NaN₃

\text{Mass of NaN}_{3} = \text{0.3332 mol NaN}_{3} \times \dfrac{\text{65.01 g NaN}_{3}}{\text{1 mol NaN}_{3}} =\textbf{21.7 g NaN}_{3}\\\\\text{You must use }\boxed{\textbf{21.7 g NaN}_{3}}

(c)Mass of NaN₃

(i) Volume of N₂

V = \text{13.0 ft}^{3} \times \dfrac{\text{28.32 L}}{\text{1 ft}^{3}} = \text{368.2 L}

(ii) Mass of N₂

\text{Mass of N}_{2} = \text{368.2 L N}_{2} \times \dfrac{\text{1.25 g N}_{2}}{\text{1 L N}_{2}} = \text{460.2 g N}_{2}

(iii) Moles of N₂

\text{Moles of N}_{2} = \text{460.2 g N}_{2} \times \dfrac{\text{1 mol N}_{2}}{\text{ 28.01 g N}_{2}} = \text{16.43 mol N}_{2}

(iv) Moles of NaN₃

\text{Moles of NaN}_{3} =\text{16.43 mol N}_{2} \times \dfrac{\text{2 mol NaN}_{3}}{\text{3 mol N}_{2}} = \text{10.95 mol NaN}_{3}

(v) Mass of NaN₃

\text{Mass of NaN}_{3} = \text{10.95 mol NaN}_{3} \times \dfrac{\text{65.01 g NaN}_{3}}{\text{1 mol NaN}_{3}} =\textbf{712 g NaN}_{3}\\\\\text{You must use }\boxed{\textbf{712 g NaN}_{3}}

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A 0.4647-g sample of a compound known to contain only carbon, hydrogen, and oxygen was burned in oxygen to yield 0.01962 mol of
Stella [2.4K]

Answer:

See explanation.

Explanation:

Hello,

In this case, we can show how the empirical formula is found by following the shown below procedure:

1. Compute the moles of carbon in carbon dioxide as the only source of carbon at the products:

n_C=0.01962molCO_2*\frac{1molC}{1molCO_2} =0.01962molC

2. Compute the moles of hydrogen in water as the only source of hydrogen at the products:

n_H=0.01961molH_2O*\frac{2molH}{1molH_2O}=0.03922molH

3. Compute the mass of oxygen by subtracting the mass of both carbon and hydrogen from the 0.4647-g sample:

m_O=0.4647g-0.01962molC*\frac{12gC}{1molC}-0.03922molH*\frac{1gH}{1molH}  =0.1900gO

4. Compute the moles of oxygen by using its molar mass:

n_O=0.1900gO*\frac{1molO}{16gO}=0.01188molO

5. Divide the moles of carbon, hydrogen and oxygen by the moles of oxygen (smallest one) to find the subscripts in the empirical formula:

C=\frac{0.01962}{0.01188}=1.65\\ \\H=\frac{0.03922}{0.01188} =3.3\\\\O=\frac{0.01188}{0.01188} =1

6. Search for the closest whole number (in this case multiply by 2):

C_3H_6O_2

Moreover, the empirical formula suggests this compound could be carboxylic acid since it has two oxygen atoms, nevertheless, this is not true since the molar mass is 222.27 g/mol, therefore, we should compute the molar mass of the empirical formula, that is:

M=12*3+1*6+16*2=74g/mol

Which is about three times in the molecular formula, for that reason, the actual formula is:

C_9H_{18}O_6

It suggest that the compound has a highly oxidizing character due to the presence of oxygen, therefore, we cannot predict the distribution of the functional groups as it could contain, carboxyl, carbonyl, hydroxyl or even peroxi.

Best regards.

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What are the limitations of litmus paper and Phenolphthalein indicators? Name to other indicators that can be used that do not h
jenyasd209 [6]

Answer:

Here's what I find.

Explanation:

An indicator is usually is a weak acid in which the acid and base forms have different colours. Most indicators change colour over a narrow pH range.

(a) Litmus

Litmus is red in acid (< pH 5) and blue in base (> pH 8).

This is a rather wide pH range, so litmus is not much good in titrations.

However, the range is which it changes colour includes pH 7 (neutral), so it is good for distinguishing between acids and bases.

(b) Phenolphthalein

Phenolphthalein  is colourless in acid (< pH 8.3) and red in base (> pH 10).

This is a narrow pH range, so phenolphthalein is good for titrating acids with strong bases..

However, it can't distinguish between acids and weakly basic solutions.

It would be colourless in a strongly acid solution with pH =1 and in a basic solution with pH = 8.

(c) Other indicators  

Other acid-base indicators have the general limitations as phenolphthalein. Most of them have a small pH range, so they are useful in acid-base titrations.

The only one that could serve as a general acid-base indicator is bromothymol blue, which has a pH range of 6.0 to 7.6.

5 0
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