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natima [27]
3 years ago
5

Automotive air bags inflate when sodium azide, NaN3, rapidly decomposes to its component elements: 2NaN3(s)→2Na(s)+3N2(g)

Chemistry
1 answer:
Brums [2.3K]3 years ago
8 0

Answer:

\boxed{\text{(a) 2.85 mol; (b) 21.7 g; (c) 712 g}}

Explanation:

We will need a balanced chemical equation with molar masses, volumes, and concentrations, so, let's gather all the information in one place.

M_r:     65.01                         28.01

         2NaN₃(s) ⟶ 2Na(s) + 3N₂(g)

n/mol:   1.90

m/g:                                        14.0

(a) Moles of N₂

The molar ratio is 3 mol N₂ = 2 mol NaN₃

\text{Moles of N}_{2} = \text{1.90 mol NaN$_{3}$}\times \dfrac{\text{3 mol N}_{2}}{\text{2 mol NaN$_{3}$}}= \textbf{2.85 mol N}_{2}\\\\\text{The reaction produces $\boxed{\textbf{2.85 mol N}_{2}}$}

(b) Mass of NaN₃

(i) Moles of N₂

\text{Moles of N}_{2} = \text{14.0 g N}_{2} \times \dfrac{\text{1 mol N}_{2}}{\text{ 28.01 g N}_{2}} = \text{0.4998 mol N}_{2}

(ii) Moles of NaN₃

\text{Moles of NaN}_{3} =\text{0.4998 mol N}_{2} \times \dfrac{\text{2 mol NaN}_{3}}{\text{3 mol N}_{2}} = \text{0.3332 mol NaN}_{3}

(iii) Mass of NaN₃

\text{Mass of NaN}_{3} = \text{0.3332 mol NaN}_{3} \times \dfrac{\text{65.01 g NaN}_{3}}{\text{1 mol NaN}_{3}} =\textbf{21.7 g NaN}_{3}\\\\\text{You must use }\boxed{\textbf{21.7 g NaN}_{3}}

(c)Mass of NaN₃

(i) Volume of N₂

V = \text{13.0 ft}^{3} \times \dfrac{\text{28.32 L}}{\text{1 ft}^{3}} = \text{368.2 L}

(ii) Mass of N₂

\text{Mass of N}_{2} = \text{368.2 L N}_{2} \times \dfrac{\text{1.25 g N}_{2}}{\text{1 L N}_{2}} = \text{460.2 g N}_{2}

(iii) Moles of N₂

\text{Moles of N}_{2} = \text{460.2 g N}_{2} \times \dfrac{\text{1 mol N}_{2}}{\text{ 28.01 g N}_{2}} = \text{16.43 mol N}_{2}

(iv) Moles of NaN₃

\text{Moles of NaN}_{3} =\text{16.43 mol N}_{2} \times \dfrac{\text{2 mol NaN}_{3}}{\text{3 mol N}_{2}} = \text{10.95 mol NaN}_{3}

(v) Mass of NaN₃

\text{Mass of NaN}_{3} = \text{10.95 mol NaN}_{3} \times \dfrac{\text{65.01 g NaN}_{3}}{\text{1 mol NaN}_{3}} =\textbf{712 g NaN}_{3}\\\\\text{You must use }\boxed{\textbf{712 g NaN}_{3}}

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(a). The Gibbs free energy change is 2.895 kJ and its positive.

(b). The Gibbs free energy change is 34.59 J/mole

(c). The pressure is 14924 atm.

(d). The Gibbs free energy of diamond relative to graphite is 4912 J.

Explanation:

Given that,

Temperature = 298 K

Suppose, density of graphite is 2.25 g/cm³ and density of diamond is 3.51 g/cm³.

\Delta H\ for\ diamond = 1.897 kJ/mol

\Delta H\ for\ graphite = 0 kJ/mol

\Delta S\ for\ diamond = 2.38 J/(K mol)

\Delta S\ for\ graphite = 5.73 J/(K mol)

(a) We need to calculate the value of \Delta G for diamond

Using formula of Gibbs free energy change

\Delta G=\Delta H-T\Delta S

Put the value into the formula

\Delta G= (1897-0)-298\times(2.38-5.73)

\Delta G=2895.3

\Delta G=2.895\ kJ

The Gibbs free energy  change is positive.

(b). When it is compressed isothermally from 1 atm to 1000 atm

We need to calculate the change of Gibbs free energy of diamond

Using formula of gibbs free energy

\Delta S=V\times\Delta P

\Delta S=\dfrac{m}{\rho}\times\Delta P

Put the value into the formula

\Delta S=\dfrac{12\times10^{-6}}{3.51}\times999\times10130

\Delta S=34.59\ J/mole

(c). Assuming that graphite and diamond are incompressible

We need to calculate the pressure

Using formula of Gibbs free energy

\beta= \Delta G_{g}+\Delta G+\Delta G_{d}

\beta=V(-\Delta P_{g})+\Delta G+V\Delta P_{d}

\beta=\Delta P(V_{d}-V_{g})+\Delta G

Put the value into the formula

0=\Delta P(\dfrac{12\times10^{-6}}{3.51}-\dfrac{12\times10^{-6}}{2.25})\times10130+2895.3

0=-0.0194\Delta P+2895.3

\Delta P=\dfrac{2895.3}{0.0194}

\Delta P=14924\ atm

(d). Here, C_{p}=0

So, The value of \Delta H and \Delta S at 900 k will be equal at 298 K

We need to calculate the Gibbs free energy of diamond relative to graphite

Using formula of Gibbs free energy

\Delta G=\Delta H-T\Delta S

Put the value into the formula

\Delta G=(1897-0)-900\times(2.38-5.73)

\Delta G=4912\ J

Hence, (a). The Gibbs free energy change is 2.895 kJ and its positive.

(b). The Gibbs free energy change is 34.59 J/mole

(c). The pressure is 14924 atm.

(d). The Gibbs free energy of diamond relative to graphite is 4912 J.

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