Question

Aqueous concentrated nitric acid is 69% hno3 by weight and has a density of 1.42 g/ml.

Answer 1

Answer: -

15.55 M

35.325 molal

Explanation: -

Let the volume of the solution be 1000 mL.

Density of nitric acid = 1.42 g/ mL

Total Mass of nitric acid Solution = Volume of nitric acid x Density of nitric acid

= 1000 mL x 1.42 g/ mL

= 1420 g.

Percentage of HNO₃ = 69%

Amount of HNO₃ = $\frac{69} {100} x 1420 g$

= 979.8 g

Molar mass of HNO₃ = 1 x 1 + 14 x 1 + 16 x 3 = 63 g /mol

Number of moles of HNO₃ = $\frac{979.8 g}{63 g/ mol}$

= 15.55 mol

Molarity is defined as number of moles per 1000 mL

We had taken 1000 mL as volume and found it to contain 15.55 moles.

Molarity of HNO₃ = 15.55 M

Mass of water = Total mass of nitric acid solution - mass of nitric acid

= 1420 - 979.8

= 440.2 g

So we see that 440.2 g of water contains 15.55 moles of HNO₃

Molality is defined as number of moles of HNO₃ present per 1000 g of water.

Molality of HNO₃ = $\frac{15.55 x 1000}{440.2}$

= 35.325 molal