Which of the following equations is balanced in a basic solution? A. ClO-(aq) + 2H-(aq) + 2e- Cl-(aq) + H2O(l) B. ClO-(aq) + H2O
2 answers:
Answer : The correct option is, (D)
Explanation :
Rules for the balanced chemical equation in basic solution are :
- First we have to write the unbalanced chemical reaction.
- Now balance the main atoms in the reaction.
- Now balance the hydrogen and oxygen atoms on both the sides of the reaction.
- If the oxygen atoms are not balanced on both the sides then adding water molecules at that side where the more number of oxygen are present.
- If the hydrogen atoms are not balanced on both the sides then adding hydroxide ion
at that side where the less number of hydrogen are present.
- Now balance the charge.
The balanced chemical equation in a basic solution will be,
Hence, the correct option is, (D)
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Answer:
Here's what I get
Explanation:
(a) Intermediates
The three structures below represent one contributor to the resonance-stabilized intermediate, in which the lone pair electrons on the heteroatom are participating (the + charge on the heteroatoms do not show up very well).
(b) Relative Stabilities
The relative stabilities decrease in the order shown.
N is more basic than O, so NH₂ is the best electron donating group (EDG) and will best stabilize the positive charge in the ring. However, the lone pair electrons on the N in acetanilide are also involved in resonance with the carbonyl group, so they are not as available for stabilization of the ring.
(c) Relative reactivities
The relative reactivities would be
C₆H₅-NH₂ > C₆H₅-OCH₃ > C₆H₅-NHCOCH₃
