Answer:
The molarity (M) of the following solutions are :
A. M = 0.88 M
B. M = 0.76 M
Explanation:
A. Molarity (M) of 19.2 g of Al(OH)3 dissolved in water to make 280 mL of solution.
Molar mass of Al(OH)3 = Mass of Al + 3(mass of O + mass of H)
= 27 + 3(16 + 1)
= 27 + 3(17) = 27 + 51
= 78 g/mole
= 78 g/mole
Given mass= 19.2 g/mole


Moles = 0.246

Volume = 280 mL = 0.280 L

Molarity = 0.879 M
Molarity = 0.88 M
B .The molarity (M) of a 2.6 L solution made with 235.9 g of KBr
Molar mass of KBr = 119 g/mole
Given mass = 235.9 g

Moles = 1.98
Volume = 2.6 L


Molarity = 0.762 M
Molarity = 0.76 M
One would be phosporous whose configuration is 1s2 2s2 2p6 3s2 3p3
Answers and Explanation:
a)- The chemical equation for the corresponden equilibrium of Ka1 is:
2. HNO2(aq)⇌H+(aq)+NO−2
Because Ka1 correspond to a dissociation equilibrium. Nitrous acid (HNO₂) losses a proton (H⁺) and gives the monovalent anion NO₂⁻.
b)- The relation between Ka and the free energy change (ΔG) is given by the following equation:
ΔG= ΔGº + RT ln Q
Where T is the temperature (T= 25ºc= 298 K) and R is the gases constant (8.314 J/K.mol)
At the equilibrium: ΔG=0 and Q= Ka. So, we can calculate ΔGº by introducing the value of Ka:
⇒ 0 = ΔGº + RT ln Ka
ΔGº= - RT ln Ka
ΔGº= -8.314 J/K.mol x 298 K x ln (4.5 10⁻⁴)
ΔGº= 19092.8 J/mol
c)- According to the previous demonstation, at equilibrium ΔG= 0.
d)- In a non-equilibrium condition, we have Q which is calculated with the concentrations of products and reactions in a non equilibrium state:
ΔG= ΔGº + RT ln Q
Q= ((H⁺) (NO₂⁻))/(HNO₂)
Q= ( (5.9 10⁻² M) x (6.7 10⁻⁴ M) ) / (0.21 M)
Q= 1.88 10⁻⁴
We know that ΔGº= 19092.8 J/mol, so:
ΔG= ΔGº + RT ln Q
ΔG= 19092.8 J/mol + (8.314 J/K.mol x 298 K x ln (1.88 10⁻⁴)
ΔG= -2162.4 J/mol
Notice that ΔG<0, so the process is spontaneous in that direction.