How many atoms are represented by one formula unit of aluminum carbonate A12(CO2)3
2 answers:
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Answer:
0.013%
Yes, it does. The answer agrees with the statement.
Explanation:
Both conformers are in equilibrium, and it can be represented by the equilibrium equation K:
K = [twist-boat]/[chair]
The free energy between them can be calculated by:
ΔG° = -RTlnK
Where R is the gas constant (8.314 J/mol.K), and T is the temperature (25°C + 273 = 298 K).
ΔG° = 5.3 kcal/mol * 4.182 kJ/kcal = 22.165 kJ/mol = 22165 J/mol
22165 = -8.314*298*lnK
-2477.572lnK = 22165
lnK = -8.946
K =
K = 1.30x10⁻⁴
[twist-boat]/[chair] = 1.30x10⁻⁴
[twist-boat] = 1.30x10⁻⁴[chair]
The percentage of the twist-boat conformer is:
[twist-boat]/([twist-boat] + [chair]) * 100%
1.30x10⁻⁴[chair]/(1.30x10⁻⁴[chair] + [chair]) *100%
0.013%
The statement about the conformers is that the chair conformer is more stable, and because of that is more present. So, the answer agrees with it.
The (( mole calcium ))s are simplified so the answer is based on the number of calcium atoms.
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