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3 years ago

What is a property in chemistry

1 answer:

3 0

DescriptionA chemical property is any of a material's properties that becomes evident during, or after, a chemical reaction; that is, any quality that can be established only by changing a substance's chemical identity.

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The process in which rock fragments freeze to the bottom of a glacier and then are carried away when the glacier moves is called

guapka [62]

Im pretty sure its called plucking

3 0

3 years ago

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The unit cell for cr2o3 has hexagonal symmetry with lattice parameters a = 0.4961 nm and c = 1.360 nm. If the density of this ma

IRINA_888 [86]

To calculate the packing factor, first calculate the area and volume of unit cell.

Area is calculated as:

$A=6R^{2}\sqrt{3}$

Here, R is radius and is related to a as follows:

$R=\frac{a}{2}$

Putting the value in expression for area,

$A=6(\frac{a}{2})^{2}\sqrt{3}=1.5a^{2}\sqrt{3}$

The value of a is 0.4961 nm

Since, $1 nm=10^{-7}cm$

Thus, $0.4961 nm=4.961\times 10^{-8} cm$

Putting the value,

$Area=1.5(4.961\times 10^{-8}cm)^{2}\sqrt{3}=6.39\times 10^{-15}cm^{2}$

Now, volume can be calculated as follows:

$V=Area\times c$

The value of c is 1.360 nm or $1.360\times 10^{-7} cm$

Putting the value,

$V=(6.39\times 10^{-15}cm^{2})\times (1.360\times 10^{-7} cm)=8.7\times 10^{-22}cm^{3}$

now, number of atom in unit cell can be calculated by using the following formula:

$n=\frac{\rho N_{A}V_{c}}{A}$

Here, A is atomic mass of $Cr_{2}O_{3}$ is 151.99 g/mol.

Putting all the values,

$n=\frac{(5.22 g/cm^{3})(6.023\times 10^{23} mol^{-1})(8.7\times 10^{-22}cm^{3})}{(151.99 g/mol)}\approx 18$

Thus, there will be 18 $Cr_{2}O_{3}$ units in 1 unit cell.

Since, there are 2 Cr atoms and 3 oxygen atoms thus, units of chromium and oxygen will be 2×18=36 and 3×18=54 respectively.

The atomic radii of $Cr^{3+}$ and $O^{2-}$ is 62 pm and 140 pm respectively.

Converting them into cm:

$1 pm=10^{-10}cm$

Thus,

$r_{Cr^{3+}}=6.2\times 10^{-9}cm$

and,

$r_{O^{2-}}=1.4\times 10^{-8}cm$

Volume of sphere will be sum of volume of total number of cations and anions thus,

$V_{S}=V_{Cr^{3+}}+V_{O^{2-}}$

Since, volume of sphere is $V=\frac{4}{3}\pi r^{3}$ ,

$V_{S}=36\left ( \frac{4}{3}\pi (r_{Cr^{3+})^{3}} \right )+54\left ( \frac{4}{3}\pi (r_{O^{2-})^{3}} \right )$

Putting the values,

$V_{S}=36\left ( \frac{4}{3}(3.14) (6.2\times 10^{-9} cm)^{3}} \right )+54\left ( \frac{4}{3}(3.14) (1.4\times 10^{-8} cm)^{3}} \right )=6.6\times 10^{-22}\times 10^{-8}cm^{3}$

The atomic packing factor is ratio of volume of sphere and volume of crystal, thus,

$packing factor=\frac{V_{S}}{V_{C}}=\frac{6.6\times 10^{-22}cm^{3}}{8.7\times 10^{-22}cm^{3}}=0.758$

Thus, atomic packing factor is 0.758.

6 0

3 years ago

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A standard solution of FeSCN2+ is prepared by combining 9.0 mL of 0.20 M Fe(NO3)3 with 1.0 mL of 0.0020 M KSCN . The standard so

Xelga [282]

Answer : The equilibrium concentration of $SCN^-$ in the trial solution is $4.58\times 10^{-8}M$

Explanation :

First we have to calculate the initial moles of $Fe^{3+}$ and $SCN^-$ .

$\text{Moles of }Fe^{3+}=\text{Concentration of }Fe^{3+}\times \text{Volume of solution}$

$\text{Moles of }Fe^{3+}=0.20M\times 9.0mL=1.8mmol$

and,

$\text{Moles of }SCN^-=\text{Concentration of }SCN^-\times \text{Volume of solution}$

$\text{Moles of }SCN^-=0.0020M\times 1.0mL=0.0020mmol$

The given balanced chemical reaction is,

$Fe^{3+}(aq)+SCN^-(aq)\rightleftharpoons FeSCN^{2+}(aq)$

Since 1 mole of $Fe^{3+}$ reacts with 1 mole of $SCN^-$ to give 1 mole of $FeSCN^{2+}$

The limiting reagent is, $SCN^-$

So, the number of moles of $FeSCN^{2+}$ = 0.0020 mmole

Now we have to calculate the concentration of $FeSCN^{2+}$ .

$\text{Concentration of }FeSCN^{2+}=\frac{0.0020mmol}{9.0mL+1.0mL}=0.00020M$

Using Beer-Lambert's law :

$A=\epsilon \times C\times l$

where,

A = absorbance of solution

C = concentration of solution

l = path length

$\epsilon$ = molar absorptivity coefficient

$\epsilon$ and l are same for stock solution and dilute solution. So,

$\epsilon l=\frac{A}{C}=\frac{0.480}{0.00020M}=2400M^{-1}$

For trial solution:

The equilibrium concentration of $SCN^-$ is,

$[SCN^-]_{eqm}=[SCN^-]_{initial}-[FeSCN^{2+}]$

$[SCN^-]_{initial}$ = 0.00050 M

Now calculate the $[FeSCN^{2+}]$ .

$C=\frac{A}{\epsilon l}=\frac{0.220}{2400M^{-1}}=9.17\times 10^{-5}M$

Now calculate the concentration of $SCN^-$ .

$[SCN^-]_{eqm}=[SCN^-]_{initial}-[FeSCN^{2+}]$

$[SCN^-]_{eqm}=(0.00050M)-(9.17\times 10^{-5}M)$

$[SCN^-]_{eqm}=4.58\times 10^{-8}M$

Therefore, the equilibrium concentration of $SCN^-$ in the trial solution is $4.58\times 10^{-8}M$

5 0

3 years ago

Which correctly describes the reaction between potassium and excess water?

nika2105 [10]

Balanced chemical reaction: 2K(s) + 2H₂O(l) → 2KOH(aq) + H₂(g).

KOH is inorganic compound p<span>otassium hydroxide, a strong base.
H</span>₂ is hydrogen gas.
In balanced chemical reaction number of atoms on both side of chemical reaction must be same. There are two potassium atoms, four hydrogen atoms and two oxygen atoms on both side of reaction.

7 0

3 years ago

- a) write the formula unit of calcium fluoride.

8090 [49]

Answer:

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5 0

2 years ago