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2 years ago

7

Which chemical equation below is balanced correctly? Al4C3 + 12H2O yields 3CH4 + 4Al(OH)3 NaCl + CaO yields Na2O + CaCl2 3LiOH +

Fe(NO3)3 yields 2LiNO3 + Fe(OH)3 Zn + 2HCl yields ZnCl2 + 2H2

1 answer:

Lisa [10]2 years ago

7 0

<span>Al4C3 + 12H2O yields 3CH4 + 4Al(OH)3 is the balanced equation.

Hope this helps!</span>

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. Determine the standard free energy change, ɔ(G p for the formation of S2−(aq) given that the ɔ(G p for Ag+(aq) and Ag2S(s) are

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<u>Answer:</u> The standard free energy change of formation of $S^{2-}(aq.)$ is 92.094 kJ/mol

<u>Explanation:</u>

We are given:

$K_{sp}\text{ of }Ag_2S=8\times 10^{-51}$

Relation between standard Gibbs free energy and equilibrium constant follows:

$\Delta G^o=-RT\ln K$

where,

$\Delta G^o$ = standard Gibbs free energy = ?

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T = temperature = $25^oC=[273+25]K=298K$

K = equilibrium constant or solubility product = $8\times 10^{-51}$

Putting values in above equation, we get:

$\Delta G^o=-(8.314J/K.mol)\times 298K\times \ln (8\times 10^{-51})\\\\\Delta G^o=285793.9J/mol=285.794kJ$

For the given chemical equation:

$Ag_2S(s)\rightleftharpoons 2Ag^+(aq.)+S^{2-}(aq.)$

The equation used to calculate Gibbs free change is of a reaction is:

$\Delta G^o_{rxn}=\sum [n\times \Delta G^o_f_{(product)}]-\sum [n\times \Delta G^o_f_{(reactant)}]$

The equation for the Gibbs free energy change of the above reaction is:

$\Delta G^o_{rxn}=[(2\times \Delta G^o_f_{(Ag^+(aq.))})+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times \Delta G^o_f_{(Ag_2S(s))})]$

We are given:

$\Delta G^o_f_{(Ag_2S(s))}=-39.5kJ/mol\\\Delta G^o_f_{(Ag^+(aq.))}=77.1kJ/mol\\\Delta G^o=285.794kJ$

Putting values in above equation, we get:

$285.794=[(2\times 77.1)+(1\times \Delta G^o_f_{(S^{2-}(aq.))})]-[(1\times (-39.5))]\\\\\Delta G^o_f_{(S^{2-}(aq.))=92.094J/mol$

Hence, the standard free energy change of formation of $S^{2-}(aq.)$ is 92.094 kJ/mol

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