If you have a book, read it!! I promise you, it tells you this answer!
n = m / M
Where, n is moles of the compound (mol), m is the mass of the compound (g) and M is the molar mass of the compound (g/mol)
Here, the given ethanol mass = 50.0 kg = 50.0 x 10³ g
Molar mass of the ethanol = (12 x 2 + 1x 6 + 1 x 16) g/mol
= 46 g/mol
Hence, moles in 50.0kg of ethanol = 50.0 x 10³ g / 46 g/mol
= 1086.96 mol
Answer: The mass of lead deposited on the cathode of the battery is 1.523 g.
Explanation:
Given: Current = 62.0 A
Time = 23.0 sec
Formula used to calculate charge is as follows.

where,
Q = charge
I = current
t = time
Substitute the values into above formula as follows.

It is known that 1 mole of a substance tends to deposit a charge of 96500 C. Therefore, number of moles obtained by 1426 C of charge is as follows.

The oxidation state of Pb in
is 2. So, moles deposited by Pb is as follows.

It is known that molar mass of lead (Pb) is 207.2 g/mol. Now, mass of lead is calculated as follows.

Thus, we can conclude that the mass of lead deposited on the cathode of the battery is 1.523 g.