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hammer [34]
2 years ago
14

Sodium phosphate is added to a solution that contains 0.0030 M aluminum nitrate and 0.016 M calcium chloride. The concentration

of the first ion to precipitate (either Al3+ or Ca2+) decreases as its precipitate forms. What is the concentration of this ion when the second ion begins to precipitate?
Chemistry
1 answer:
gavmur [86]2 years ago
7 0

Explanation:

It is given that aluminium nitrate and calcium chloride are mixed together with sodium phosphate.

And, K_{sp} of AlPO_{4} = 9.84 \times 10^{-21}

        K_{sp} of Ca_{3}(PO_{4})_{2} = 2.0 \times 10^{-29}

Let us assume that the solubility be "s". And, the reaction equation is as follows.

        AlPO_{4} \rightleftharpoons Al^{3+} + PO^{3-}_{4}

     9.84 \times 10^{-21} = s \times s

             s = 9.92 \times 10^{-11}

Also,     Ca_{3}(PO_{4})_{2} \rightleftharpoons 3Ca^{2+} + 2PO^{3-}_{4}

                2 \times 10^{-29} = (3s)^{3} \times (2s)^{2}

                            s = 7.14 \times 10^{-7}

This means that first, aluminium phosphate will precipitate.

Now, we will calculate the concentration of phosphate when calcium phosphate starts to precipitate out using the K_{sp} expression as follows.

         K_{sp} = [Ca^{2+}]^{3}[PO^{3-}_{4}]^{2}

          2.0 \times 10^{-29} = (0.016)^{3}[PO^{3-}_{4}]^{2}

       2.0 \times 10^{-29} = 4.096 \times 10^{-6} \times [PO^{3-}_{4}]^{2}

       [PO^{3-}_{4}]^{2} = 4.88 \times 10^{-24}

                             = 2.21 \times 10^{-12} M

Similarly, calculate the concentration of aluminium at this concentration of phosphate as follows.

             AlPO_{4} \rightleftharpoons Al^{3+} + PO^{3-}_{4}

           K_{sp} = [Al^{3+}][PO^{3-}_{4}]

       9.84 \times 10^{-21} = [Al^{3+}] \times 2.21 \times 10^{-12}

                [Al^{3+}] = 4.45 \times 10^{-9} M

Thus, we can conclude that concentration of aluminium will be 4.45 \times 10^{-9} M when calcium begins to precipitate.

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Vapor obtained by evaporating 0.495 grams of an unknown liquid is collected in a 127 mL flask. At 371 K, the pressure of the vap
lidiya [134]

Answer:

The molar mass in g/mol is 121.4 g/m

Explanation:

Let's apply the Ideal Gases Law to solve this:

P . V = n . R. T

V = 125 mL → 0.125L

P = 754 Torr

760 Torr ___ 1 atm

754 Torr ____ (754 / 760) = 0.992 atm

Moles = Mass / Molar mass

0.992 atm . 0.125L = (0.495 g / MM) . 0.082 . 371K

(0.992 atm . 0.125L) / (0.082 . 371K) = (0.495 g / MM)

4.07x10⁻³ mol = 0.495 g / MM

MM = 0.495 g / 4.07x10⁻³ mol → 121.4 g/m

3 0
2 years ago
3.
Alecsey [184]

Answer:

<h3>no it is not allowed</h3>

Explanation:

<h3>Liwis structure shows the elements symbol with dots thet represents valance electrons ; in second row elements their atomic number is 3 up to 10 , from Li up to Ne from their electron configuration their valance electron will be from 1 up to 8 respectivelly ,if lewis structure represents the element with it is symbol and dots that represents valance electron the second row elements cannot have more than an octet of valance electrons surrounding it.</h3>

<h3>I think it is help ful for you </h3>
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2 years ago
Plsssss give me answer<br>​
34kurt

Explanation:

Medieval number one. There you havt it.

4 0
1 year ago
In a laboratory experiment, John uses a mesh to separate soil particles from water. Which technique of separation is he using?
Aneli [31]
Salutations!

<span>In a laboratory experiment, John uses a mesh to separate soil particles from water. Which technique of separation is he using?

The technique that John is using is the filtration technique. Filtration is a technique to separate the solid which is insoluble from the liquid. For instance: Sand and water, sand is insoluble, thus it stays in the filter paper, while the water proceeds through the filter paper.

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3 years ago
Can someone help me with these questions?
Gennadij [26K]

Answer:

9) Substitution Reaction

10) Covalent Bond

11) Ionic Bond

12) Covalent Bond

13) Ionic Bond

14) 9 atoms

Explanation:

9) Substitution Reaction: Substitution reaction is a chemical reaction in which one atom, ion or species replaced by another atom, ion or species

10) Covalent Bond: Covalent bond is a bond that formed between two nonmetals, when both the species are non metal, the electronegativity of both the nonmetals are comparatively same, hence any of both do not pulls completely electron of other & the bond is formed by the sharing of electron.

11) Ionic Bond: We know that nonmetals have high electronegativity than those of metals, due to high electronegativity non metals pulls the electrons of metals but there is enough interaction that non metal do not escape after pulling the electron, & an ionic bond generates where non metals possess negative charge & positive charge goes to metal.

12) Covalent Bond: The bond formed between two atoms having less electronegativity diffrence by sharing of electron pair is know as covalent bond. for e.g the Carbon - Hydrogen bond in methane (CH4) molecule is covalent bonded because the electronegativity of carbon is 2.5 & that of hydrogen is 2.1 which is almost close, hence the bond formed is covalent.

13) Ionic Bond: The bond formed between two atoms having high electronegativity diffrence & the bond formed is due to complete transfer of electron by one species. For e.g. NaCl the sodium is a metal having electronegativity 0.9 and chlorine is non metal having electronegativity 3.0 the electronegativity diffrence is too high, hence the chlorine behaves as Cl- ion that of sodium as Na+, both the components behaves as ion but they are bonded &that bond is called as Ionic bond.

14) 9 Atoms: One molecule of water (H2O) posses three atoms, two hydrogen atoms & one oxygen atom, the number of atoms in 3 molecules of water 3×3 = 9 atoms.

<em><u>Thanks for joining brainly community!</u></em>

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2 years ago
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