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damaskus [11]
3 years ago
7

When ethyl acetoacetate (ch3coch2co2ch2ch3) is treated with one equivalent of ch3mgbr, a gas is evolved from the reaction mixtur

e, and after adding aqueous acid, ethyl acetoacetate is recovered in high yield. identify the gas formed and explain why the starting material was recovered in this reaction. be sure to answer all parts?

Chemistry
1 answer:
pashok25 [27]3 years ago
6 0
The protons of methylene group between the two carbonyl groups in ethylacetoacetate are acidic in nature. When compounds containing such acidic protons are treated with bases the loose proton and form enolates.

In this particular example when ethylacetoacetate is reacted with methyl magnesium bromide, the methyl group abstracts the acidic proton and converts into methane gas. The enolate when hydrolyzed is again converted into ethylacetoacetate as shown below,

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an unknown amount of mercury (ii) oxide was decomposed in the lab. mercury metal was formed and 4.50 l of oxygen gas was release
Assoli18 [71]

The initial weight of mercury oxide in the sample was 59.1 g HgO.

<h3>Steps</h3>

chemical reaction

2HgO ⟶ 2Hg + O₂

the moles of O₂

pV = nRT

n = (pV)/(RT)

Data:

p = 0.970 atm

V = 4.50 L

R = 0.082 06 L·atm·K⁻¹mol⁻¹

T = 390.0 K

Calculation:

n = (0.970 × 4.500)/(0.082 06 × 390.0)

n = 0.1364 mol O₂

the moles of HgO

The molar ratio is 1 mol O₂/2 mol HgO.

Moles of HgO = 0.1364 mol O₂ × (2 mol Hg/1 mol O₂)

Moles of HgO = 0.2728 mol HgO

the mass of HgO

Mass of HgO = 0.2728 mol HgO × (216.59 g HgO/1 mol HgO)

Mass of HgO = 59.1 g HgO

<h3>What is the name of HgO?</h3>

For the creation of various organic mercury compounds and specific inorganic mercury salts, mercury(II) oxide, or HgO, serves as a source of elemental mercury.

This red or yellow crystalline substance is also utilised in mercury batteries and zinc-mercuric oxide electric cells as an electrode (combined with graphite).

<h3>What is the purpose of mercury oxide?</h3>

Mercuric oxide is a colourless, crystalline powder that ranges from yellow to orange-yellow.

It serves as a seed protectant, a pigment, a preservative, and an ingredient in alkaline batteries and cosmetics.

<h3>Is there a combination of mercury oxide?</h3>
  • The powder form of mercury oxide is dark black or dark brown.
  • An intimate blend of metallic mercury and mercuric oxide rather than a genuine compound.

learn more about mercury oxide here

brainly.com/question/3235037

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<span>Enthalpy is regarding the amount of heat that is given off or taken in during the process of a reaction, while entropy is about the disorderliness of a reaction. 
Both are related in the equation ∆G=∆H-T∆S, where ∆G is the Gibbs free energy. So we can say that a reaction is both enthalpy and entropy driven. It's like, both of them are interlinked with each other. </span>
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