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damaskus [11]
3 years ago
7

When ethyl acetoacetate (ch3coch2co2ch2ch3) is treated with one equivalent of ch3mgbr, a gas is evolved from the reaction mixtur

e, and after adding aqueous acid, ethyl acetoacetate is recovered in high yield. identify the gas formed and explain why the starting material was recovered in this reaction. be sure to answer all parts?

Chemistry
1 answer:
pashok25 [27]3 years ago
6 0
The protons of methylene group between the two carbonyl groups in ethylacetoacetate are acidic in nature. When compounds containing such acidic protons are treated with bases the loose proton and form enolates.

In this particular example when ethylacetoacetate is reacted with methyl magnesium bromide, the methyl group abstracts the acidic proton and converts into methane gas. The enolate when hydrolyzed is again converted into ethylacetoacetate as shown below,

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(2 KClO3 (s) → 2 KCl (s) + 3 O2 (g) ) If 165 mL of oxygen is produced at 30.0 °C and 90.0 kPa, what mass of KClO3 was decomposed
soldier1979 [14.2K]

Taking into account the reaction stoichiometry and ideal gas law, 0.48144 grams of KClO₃ was decomposed.

<h3>Reaction stoichiometry</h3>

In first place, the balanced reaction is:

2 KClO₃  → 2 KCl + 3 O₂

By reaction stoichiometry (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

  • KClO₃: 2 moles  
  • KCl: 2 moles
  • O₂: 3 moles

The molar mass of the compounds is:

  • KClO₃: 122.45 g/mole
  • KCl: 74.45 g/mole
  • O₂: 32 g/mole

Then, by reaction stoichiometry, the following mass quantities of each compound participate in the reaction:

  • KClO₃: 2 moles ×122.45 g/mole= 244.8 grams
  • KCl: 2 moles ×74.45 g/mole= 148.9 grams
  • O₂: 3 moles ×32 g/mole= 96 grams

<h3>Ideal gas law</h3>

The pressure, P, the temperature, T, and the volume, V, of an ideal gas, are related by a simple formula called the ideal gas law:

P×V = n×R×T

where:

  • P is the gas pressure.
  • V is the volume that the gas occupies.
  • T is the temperature of the gas.
  • R is the ideal gas constant. The universal constant of ideal gases R has the same value for all gaseous substances.
  • n is the number of moles of the gas.

<h3>Number of O₂ produced.</h3>

165 mL of oxygen is produced at 30.0 °C and 90.0 kPa. This is, you know:

  • P= 90 kPa= 0.888231 atm (being 101.325 kPa= 1 atm)
  • V= 165 mL= 0.165 L (being 1000 mL= 1 L)
  • n= ?
  • R= 0.082 \frac{atmL}{molK}
  • T= 30 C= 303 K (being 0 C= 273 K)

Replacing in the ideal gas law:

0.888231 atm× 0.165 L = n× 0.082 \frac{atmL}{molK}× 303 K

Solving:

n= (0.888231 atm× 0.165 L)÷ (0.082 \frac{atmL}{molK}× 303 K)

<u><em>n= 0.0059 moles</em></u>

Finally, 0.0059 moles of oxygen is produced at 30 °C and 90 kPa.

<h3>Mass of KClO₃ required</h3>

The following rule of three can be applied: If by stoichiometry of the reaction 3 moles of O₂ are produced by 244.8 grams of KClO₃, 0.0059 moles of O₂ are produced by how much mass of KClO₃?

mass of KClO_{3}= \frac{0.0059 moles of O_{2}x 244.8 grams of KClO_{3}}{3 moles of O_{2}}

<u><em>mass of KClO₃= 0.48144 grams</em></u>

Finally, 0.48144 grams of KClO₃ was decomposed.

Learn more about

the reaction stoichiometry:

<u>brainly.com/question/24741074</u>

<u>brainly.com/question/24653699</u>

ideal gas law:

<u>brainly.com/question/4147359?referrer=searchResults</u>

4 0
2 years ago
HURRY PLEAS!!!!!!!!!!!!!!!!!!!!
mixas84 [53]
D. action force and reaction forces are stated in his law
8 0
3 years ago
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3. Why does å star begin shining?
steposvetlana [31]

Answer:

a star shines due to thermonuclear fusion

Explanation:

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3 years ago
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How much heat is evolved in converting 1.00 mol of steam at 155.0 ∘c to ice at -50.0 ∘c? the heat capacity of steam is 2.01 j/(g
Ne4ueva [31]
When the specific heat capacity of the water is 4.18 J/g.°C so, we are going to use this formula to get the heat for cooling three  phases changes from steam to liquid and from liquid to ice (solid) :

when Q = M*C*ΔT 

Q is the heat in J

and M is the mass in gram = 1 mol H2O * 18 g/mol(molar mass) = 18 g

C is the specific heat J/g.°C

ΔT is the change in temperature

Q = Mw *[ ( Csteam * ΔTsteam)+(Cw*ΔTw) + (Cice  * ΔT ice)]

    = 18 g * [(2.01 * (155-100°C)) + (4.18 * (100-0°C)) + (2.09 * (0 - 55 °C))]

∴Q = 7444.8 J

and when we know that the heat of fusion for water = 334J/g

and heat of vaporization for water =  2260J/g


∴Q for the two phases changes = M * (2260+334) 

                                                      = 18 * (2260+334)

                                                      = 46692 J 

∴ Q total = 7444.8 + 46692 = 54136.8 J
5 0
3 years ago
What element is primarily used in appliances to make electronic chips
sineoko [7]

Answer:

Option A

Explanation:

Silicon (Obtained from Sand (SiO2)) is the element that is primarily used in appliances to make electronic chips.

6 0
3 years ago
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