First of all, let's count how many events compose our sample space: since we are rolling two dice, and each of them has six sides, the sample space has 36 possible events, given by all couples
, with 
Then, we observe that none of the die can give 4 or more, otherwise the sum of the two dice would be at least 5.
So, we have the following possible outcomes:
Red die gives 1, green die gives 3
Both dice give 2
Red die gives 3, green die gives 1.
These are three events out of the 36 possible events, so their probability is
