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I am Lyosha [343]
3 years ago
8

Electrochemistry - Equilibrium

Chemistry
1 answer:
Ipatiy [6.2K]3 years ago
8 0

Answer:

Explanation:

The relation between equilibrium constant and Ecell is given below .

E⁰cell = (RT / nF ) lnK  , F is faraday constant T is 273 + 25 = 298 K

E⁰cell  =  1.46 - 1.21 = .25 V

n = 2

Putting the values

.25 = (8.314 x 298  lnK) / (2 x 96485 )

lnK = 19.47

K = 2.85 x 10⁸

2 )

Change in free energy Δ G

Δ G ⁰ = nE⁰ F

n = 4

E⁰ = .4 + .83 = 1.23 V

Δ G ⁰= 4 x 1.23 x 96485

= 474706 J / mol

3 )

E⁰cell = (RT / nF ) lnK

n = 2

1.78 = 8.314 x 298  lnK / 2 x 96485

lnK = 138.638

K = 1.62 x 10⁶⁰

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Balance the following equation:
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Answer: a) 2K_2CrO_4+3Na_2SO_3+10HCl\rightarrow 4KCl+3Na_2SO_4+2CrCl_3+5H_2O

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Explanation:

According to the law of conservation of mass, mass can neither be created nor be destroyed. Thus the mass of products has to be equal to the mass of reactants. The number of atoms of each element has to be same on reactant and product side. Thus chemical equations are balanced.

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Post-Lab Questions
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