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Wittaler [7]
3 years ago
15

Select the correct balanced oxidation-reduction reaction. Group of answer choices 14H+(aq) + 6Fe2+(aq) + Cr2O72-(aq) -> 6Fe3+

(aq) + 2Cr +(aq) + 7H2O(l) 14H+(aq) + 6Fe2+(aq) + Cr2O72-(aq) -> 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(l) + 2e- 7H+(aq) + 6Fe2+(aq) + Cr2O72-(aq) -> 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(l) 14H+(aq) + 6Fe2+(aq) + Cr2O72-(aq) -> 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(l)
Chemistry
1 answer:
bezimeni [28]3 years ago
6 0

Answer:

The correct balanced oxidation- reduction reaction is:

14H+(aq) + 6Fe2+(aq) + Cr2O72-(aq) -> 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(l)

Explanation:

In this reaction, iron (Fe2+) is the reducing agent while Cr2O7^2- is the oxidizing agent.

The ion transfer is represented as shown below:

6 Fe 2+  - 6e- -----------> 6 Fe 3+          (oxidation)

2 Cr^6  + 6e^-  ----------> 2 Cr^3           (reduction)

From the unbalanced reaction

Fe2+ + Cr2O72- + H+ ---------->  Fe3+ + Cr3+ + H2O we will follow these steps to balance the reaction.

Step 1: break the equation into two half reactions stating which is oxidized and reduced.

Step 2: Balance the atoms on each sides; the hydrogen, oxygen

Step 3: Balance the gain also

Step 4: Give the electron gained on one side to be equal to the electron lost on the other side.

Step 5: Add the two half reactions and simplify the equation.

Doing this, we obtain

14H+(aq) + 6Fe2+(aq) + Cr2O72-(aq) -> 6Fe3+(aq) + 2Cr3+(aq) + 7H2O(l)

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Arrange the following H atom electron transitions in order of decreasing wavelength of the photon absorbed or emitted:
Katyanochek1 [597]

The decreasing order of wavelengths of the photons emitted or absorbed by the H atom is : b → c → a → d

Rydberg's formula :

                                   \frac{1}{\lambda} = R_h (\frac{1}{n_1^2}-\frac{1}{n_2^2} ),

where  λ is the wavelength of the photon emitted or absorbed from an H atom electron transition from n_1 to n_2 and R_h = 109677 is the Rydberg Constant. Here n_1 and  n_2 represents the transitions.

(a) n_1 =2 to n_2 = infinity

            \frac{1}{\lambda} = 109677\times (\frac{1}{2^2}-\frac{1}{\infty^2}  ) = 109677/4     [since 1/infinity = 0] Therefore, \lambda = 4 / 109677 = 0.00003647 m

(b) n_1=4 to  n_2 = 20

           \frac{1}{\lambda} = 109677\times (\frac{1}{4^2}-\frac{1}{20^2}  ) = 6580.62

Therefore,  \lambda = 1 / 6580.62 = 0.000152 m

(c) n_1=3 to  n_2 = 10

          \frac{1}{\lambda} = 109677\times (\frac{1}{3^2}-\frac{1}{10^2}  ) = 11089.56

Therefore,  \lambda = 1 / 11089.56 = 0.00009 m

(d)  n_1=2 to  n_2 = 1

          \frac{1}{\lambda} = 109677\times (\frac{1}{2^2}-\frac{1}{1^2}  ) = - 82257.75

Therefore,  \lambda = 1 /82257.75  = - 0.0000121 m  

[Even though there is a negative sign, the magnitude is only considered because the sign denotes that energy is emitted.]

So the decreasing order of wavelength of the photon absorbed or emitted is b → c → a → d.

Learn more about the Rydberg's formula athttps://brainly.com/question/14649374

#SPJ4

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