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sukhopar [10]
3 years ago
11

Determine the vapor pressure (atm) of rubbing alcohol (isopropanol) at 20.0 °C. The normal boiling point of isopropanol is 82.3

°C and the heat of vaporization (ΔHvap) is 39.9 kJ/mol.
Chemistry
1 answer:
jeyben [28]3 years ago
8 0
Here we apply the Clausius-Clapeyron equation:
ln(P₁/P₂) = ΔH/R x (1/T₂ - 1/T₁)

The normal vapor pressure is 4.24 kPa (P₁)
The boiling point at this pressure is 293 K (P₂)
The heat of vaporization is 39.9 kJ/mol (ΔH)
We need to find the vapor pressure (P₂) at the given temperature 355.3 K (T₂)

ln(4.24/P₂) = 39.9/0.008314 x (1/355.3 - 1/293)
P₂ = 101.2 kPa
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Explanation:

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Initially:

0.15 M            0.15 M            0.40 M   0.40 M

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The equilibrium constant is given by expression

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The equilibrium concentrations for a mixture :

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Ethanol at equilibrium = (0.15-x)M = (0.15-0.033) M = 0.117 M

Ethyl acetate at equilibrium = (0.40+x)M = (0.40+0.033) M = 0.433 M

Water at equilibrium = (0.40+x)M = (0.40+0.033) M = 0.433 M

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