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Georgia [21]
3 years ago
9

Carbon dioxide (CO2) fills a closed, rigid tank fitted with a paddle wheel, initially at 80°F, 30 lbf/in2, and a volume of 1.6 f

t3. The gas is stirred until its temperature is 500°F. During this process heat transfer from the gas to its surroundings occurs in an amount 2.6 Btu. Assume ideal gas behavior, but do not assume constant specific heats. Kinetic and potential energy effects can be ignored. Determine the mass of the carbon dioxide, in lb, and the work, in Btu.
Chemistry
1 answer:
solong [7]3 years ago
8 0

Answer:

The answer to this question can be given as:  

The initial pressure P= 30 lbf/in2

The initial temperature T1=80°F.

The initial volume=final volume V= 1.6 ft3.

Final  temperature T2=500°F

Heat transfer Q=-2.6 Btu.

pressure (P) (lbf/in2) change into lbf/ft2

P=30 lbf/in2=4320lbf/ft2.

Temperature (T1) °F change into °K

temperature T1=80°F=539.67 °K

Ideal gas formula:

M=PV/RT1.                   where T1=initial temperature.

M=4320*1.6/35.114*539.67.

M=0.364749 lb             Mass at Carbon dioxide (CO2).

DQ=DU+W            second law.

-2.6=MCV(T2-T1)+ W        

-2.6-(0.364749*1.6(500-80))=W

W=-27.111 b+u  am----> work done.

Explanation:

The explanation to this question can be given as:

Firstly we write the equation that is given in the question like, pressure, volume, gas constant, temperature. Then we covert the pressure and temperature into there possible values. Then We apply the formula of Ideal gas that is  M=PV/RT1. where M is  the mass, P is the pressure , V is the volume , R is the gas constant (0.08206 L·atm·K−1·mol−1)  and T1 is the initial temperature. Then we use the second formula that is DQ=DU+W. Where DQ= Heat transfer, DU=MCV(T2-T1)and W= work. It is used for finding work.

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The composition of a liquid-phase reaction 2A - B was monitored spectrophotometrically. The following data was obtained: t/min 0
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Answer:

1) The order of the reaction is of FIRST ORDER

2)   Rate constant k = 5.667 × 10 ⁻⁴

Explanation:

From the given information:

The composition of a liquid-phase reaction 2A - B was monitored spectrophotometrically.

liquid-phase reaction 2A - B signifies that the reaction is of FIRST ORDER where the rate of this reaction is directly proportional to the concentration of A.

The following data was obtained:

t/min                    0         10         20          30             40          ∞

conc B/(mol/L)    0       0.089    0.153     0.200       0.230    0.312

For  a first order reaction:

K = \dfrac{1}{t} \ In ( \dfrac{C_{\infty} - C_o}{C_{\infty} - C_t})

where :

K = proportionality  constant or the rate constant for the specific reaction rate

t = time of reaction

C_o = initial concentration at time t

C _{\infty} = final concentration at time t

C_t = concentration at time t

To start with the value of t when t = 10 mins

K_1 = \dfrac{1}{10} \ In ( \dfrac{0.312 - 0}{0.312 - 0.089})

K_1 = \dfrac{1}{10} \ In ( \dfrac{0.312 }{0.223})

K_1 =0.03358 \  min^{-1}

K_1 \simeq 0.034 \  min^{-1}

When t = 20

K_2= \dfrac{1}{20} \ In ( \dfrac{0.312 - 0}{0.312 - 0.153})

K_2= 0.05 \times  \ In ( 1.9623)

K_2=0.03371 \ min^{-1}

K_2 \simeq 0.034 \ min^{-1}

When t = 30

K_3= \dfrac{1}{30} \ In ( \dfrac{0.312 - 0}{0.312 - 0.200})

K_3= 0.0333 \times  \ In ( \dfrac{0.312}{0.112})

K_3= 0.0333 \times  \ 1.0245

K_3 = 0.03412 \ min^{-1}

K_3 = 0.034 \ min^{-1}

When t = 40

K_4= \dfrac{1}{40} \ In ( \dfrac{0.312 - 0}{0.312 - 0.230})

K_4=0.025 \times  \ In ( \dfrac{0.312}{0.082})

K_4=0.025 \times  \ In ( 3.8048)

K_4=0.03340 \ min^{-1}

We can see that at the different time rates, the rate constant of k_1, k_2, k_3, and k_4 all have similar constant values

As such :

Rate constant k = 0.034 min⁻¹

Converting it to seconds ; we have :

60 seconds = 1 min

∴

0.034 min⁻¹ =(0.034/60) seconds

= 5.667 × 10 ⁻⁴ seconds

Rate constant k = 5.667 × 10 ⁻⁴

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