Following reaction shows the complete hydrolysis of ketal. The products formed are 1) Diol and 2) Ketone. Mechanism is shown below,
An analytical chemist is titrating of a solution of ammonia with a solution of . The of ammonia is . Calculate the pH of the bas
1 answer:
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Answer:
See the image 1
Explanation:
If you look carefully at the progress of the SN2 reaction, you will realize something very important about the outcome. The nucleophile, being an electron-rich species, must attack the electrophilic carbon from the back side relative to the location of the leaving group. Approach from the front side simply doesn't work: the leaving group - which is also an electron-rich group - blocks the way. (see image 2)
The result of this backside attack is that the stereochemical configuration at the central carbon inverts as the reaction proceeds. In a sense, the molecule is turned inside out. At the transition state, the electrophilic carbon and the three 'R' substituents all lie on the same plane. (see image 3)
What this means is that SN2 reactions whether enzyme catalyzed or not, are inherently stereoselective: when the substitution takes place at a stereocenter, we can confidently predict the stereochemical configuration of the product.
Answer:
1. AgNO₃ (aq) + NaCl (aq) ----> NaNO₃ (aq) + AgCl (s)
2. Li₂SO₄ (aq) + BaCl₂ (aq) ----> 2 LiCl (aq) + BaSO₄ (s)
3. 2 NaOH (aq) + MgCl₂ (aq) ----> 2 NaCl (aq) + Mg(OH)₂ (s)
Explanation:
The reaction involving the mixing of two soluble solutions to produce a precipitate is known as a precipitation reaction.
A precipitation reaction is double-replacement reaction (a reaction that exchanges the cations or the anions of two ionic compounds) in which one product is a solid precipitate.
Precipitation reactions at useful in the identification of various ions present in a solution. In order to predict the reactions that will produce a precipitate, solubility rules as given in the solubility table below can be used.
From the tables, the reactions that will produce a precipitate, as well as their balanced molecular equations are as follows:
1. AgNO₃ (aq) + NaCl (aq) ----> NaNO₃ (aq) + AgCl (s)
2. Li₂SO₄ (aq) + BaCl₂ (aq) ----> 2 LiCl (aq) + BaSO₄ (s)
3. 2 NaOH (aq) + MgCl₂ (aq) ----> 2 NaCl (aq) + Mg(OH)₂ (s)
