39.25 g of water (H₂O)
Explanation:
We have the following chemical reaction:
2 H₂ + O₂ → 2 H₂O
Now we calculate the number of moles of each reactant:
number of moles = mass / molar weight
number of moles of H₂ = 14.8 / 2 = 7.4 moles
number of moles of O₂ = 34.8 / 32 = 1.09 moles
We see from the chemical reaction that 2 moles of H₂ will react with 1 mole of O₂ so 7.4 moles of H₂ will react with 3.7 moles of O₂ but we only have 1.09 moles of O₂ available. The O₂ will be the limiting reactant. Knowing this we devise the following reasoning:
if 1 moles of O₂ produces 2 moles of H₂O
then 1.09 moles of O₂ produces X moles of H₂O
X = (1.09 × 2) / 1 = 2.18 moles of H₂O
mass = number of moles × molar weight
mass of H₂O = 2.18 × 18 = 39.25 g
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limiting reactant
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We have Kc = 4.2 x 10^-2 (given but missing in the question)
and When the balanced equation for this reaction is:
PCl5(g) ↔ PCl3(g) + Cl2(g)
so, according to the Kc formula:
Kc = the concentration of products / the concentration of the reactants
so, to get the concentration of the reactants in equilibrium, the concentration of the products / the concentration of the reactants should equal the Kc value which is given in the question (missing in your question).
So by substitution in Kc formula:
Kc = [PCl3]*[Cl2] / [PCl5]
4.2 x 10^-2 = 0.18 * 0.25 /[PCl5]
∴[PCl5] = 0.18*0.25 / 4.2x10^-2 = 1.07
So the concentration of the reactants in equilibrim = 1.07
Answer: 27.09 ppm and 0.003 %.
First, <u>for air pollutants, ppm refers to parts of steam or gas per million parts of contaminated air, which can be expressed as cm³ / m³. </u>Therefore, we must find the volume of CO that represents 35 mg of this gas at a temperature of -30 ° C and a pressure of 0.92 atm.
Note: we consider 35 mg since this is the acceptable hourly average concentration of CO per cubic meter m³ of contaminated air established in the "National Ambient Air Quality Objectives". The volume of these 35 mg of gas will change according to the atmospheric conditions in which they are.
So, according to the <em>law of ideal gases,</em>
PV = nRT
where P, V, n and T are the pressure, volume, moles and temperature of the gas in question while R is the constant gas (0.082057 atm L / mol K)
The moles of CO will be,
n = 35 mg x
x
→ n = 0.00125 mol
We clear V from the equation and substitute P = 0.92 atm and
T = -30 ° C + 273.15 K = 243.15 K
V = 
→ V = 0.0271 L
As 1000 cm³ = 1 L then,
V = 0.0271 L x
= 27.09 cm³
<u>Then the acceptable concentration </u><u>c</u><u> of CO in ppm is,</u>
c = 27 cm³ / m³ = 27 ppm
<u>To express this concentration in percent by volume </u>we must consider that 1 000 000 cm³ = 1 m³ to convert 27.09 cm³ in m³ and multiply the result by 100%:
c = 27.09
x
x 100%
c = 0.003 %
So, <u>the acceptable concentration of CO if the temperature is -30 °C and pressure is 0.92 atm in ppm and as a percent by volume is </u>27.09 ppm and 0.003 %.
A) Temperature does not affect reaction rate