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denpristay [2]
3 years ago
13

Show the calculation of the mass (grams) of a 14.5 liter gas sample with a molecular weight of 82 when collected at 29°C and 740

mm
Chemistry
1 answer:
mote1985 [20]3 years ago
4 0

Answer:

In this conditions, the gaswll weight 46.74 g.

Explanation:

The idal gas law states that:

PV = nRT,

P: pressure = 740 mmHg = 0.97 atm

V: volume = 14.5 L

n: number of moles

R: gas constant =0.08205 L.atm/mol.K

T: temperature = 29°C = 302.15K

n = \frac{PV}{RT} \\n = \frac{0.97x14.5}{0.082 x 302.15 } \\n = 0.57 mol

1 mol gas ___ 82 g

0.57 mol gas __ x

x = 46.74 g

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If 0.507J of heat leads to a 0.007 degree C change in water, what mass is present?
Mamont248 [21]

Answer:

17.3 g

Explanation:

<u>Given the following data;</u>

  • Quantity of heat, Q = 0.507 J
  • Temperature = 0.007°C
  • Specific heat capacity of water = 4.2 J/g°C

Mathematically, Heat capacity is given by the formula;

Q = MCT

Where;

  • Q represents the heat capacity or quantity of heat.
  • M represents the mass of an object.
  • C represents the specific heat capacity of water.
  • T represents the temperature.

Making "M" the subject of formula, we have;

M = \frac {Q}{CT}

Substituting the values into the formula, we have;

M = \frac {0.507}{4.2*0.007}

M = \frac {0.507}{0.0294}

<em>Mass, m = 17.3 grams</em>

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3 years ago
A solution contains 0.0440 M Ca2 and 0.0940 M Ag. If solid Na3PO4 is added to this mixture, which of the phosphate species would
Olenka [21]

Answer:

C. Ca_3(PO_4)_2  will precipitate out first

the percentage of Ca^{2+}remaining =  12.86%

Explanation:

Given that:

A solution contains:

[Ca^{2+}] = 0.0440 \ M

[Ag^+] = 0.0940 \ M

From the list of options , Let find the dissociation of Ag_3PO_4

Ag_3PO_4 \to Ag^{3+} + PO_4^{3-}

where;

Solubility product constant Ksp of Ag_3PO_4 is 8.89 \times 10^{-17}

Thus;

Ksp = [Ag^+]^3[PO_4^{3-}]

replacing the known values in order to determine the unknown ; we have :

8.89 \times 10 ^{-17}  = (0.0940)^3[PO_4^{3-}]

\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}  = [PO_4^{3-}]

[PO_4^{3-}] =\dfrac{8.89 \times 10 ^{-17}}{(0.0940)^3}

[PO_4^{3-}] =1.07 \times 10^{-13}

The dissociation  of Ca_3(PO_4)_2

The solubility product constant of Ca_3(PO_4)_2  is 2.07 \times 10^{-32}

The dissociation of Ca_3(PO_4)_2   is :

Ca_3(PO_4)_2 \to 3Ca^{2+} + 2 PO_{4}^{3-}

Thus;

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33} = (0.0440)^3  [PO_4^{3-}]^2

\dfrac{2.07 \times 10^{-33} }{(0.0440)^3}=   [PO_4^{3-}]^2

[PO_4^{3-}]^2 = \dfrac{2.07 \times 10^{-33} }{(0.0440)^3}

[PO_4^{3-}]^2 = 2.43 \times 10^{-29}

[PO_4^{3-}] = \sqrt{2.43 \times 10^{-29}

[PO_4^{3-}] =4.93 \times 10^{-15}

Thus; the phosphate anion needed for precipitation is smaller i.e 4.93 \times 10^{-15} in Ca_3(PO_4)_2 than  in  Ag_3PO_4  1.07 \times 10^{-13}

Therefore:

Ca_3(PO_4)_2  will precipitate out first

To determine the concentration of [Ca^+] when  the second cation starts to precipitate ; we have :

Ksp = [Ca^{2+}]^3 [PO_4^{3-}]^2

2.07 \times 10^{-33}  = [Ca^{2+}]^3 (1.07 \times 10^{-13})^2

[Ca^{2+}]^3 =  \dfrac{2.07 \times 10^{-33} }{(1.07 \times 10^{-13})^2}

[Ca^{2+}]^3 =1.808 \times 10^{-7}

[Ca^{2+}] =\sqrt[3]{1.808 \times 10^{-7}}

[Ca^{2+}] =0.00566

This implies that when the second  cation starts to precipitate ; the  concentration of [Ca^{2+}] in the solution is  0.00566

Therefore;

the percentage of Ca^{2+}  remaining = concentration remaining/initial concentration × 100%

the percentage of Ca^{2+} remaining = 0.00566/0.0440  × 100%

the percentage of Ca^{2+} remaining = 0.1286 × 100%

the percentage of Ca^{2+}remaining =  12.86%

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What's the boiling point of water at 0 atmospheric pressure?
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The water will evaporate and fly out of the bucket; the process will not stop until there is enough water vapor in the atmosphere that the vapor pressure stops the water from boiling further.

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