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pav-90 [236]
3 years ago
5

The combustion of 0.570 g of benzoic acid (ΔHcomb = 3,228 kJ/mol; MW = 122.12 g/mol) in a bomb calorimeter increased the tempera

ture of the calorimeter by 2.053naughtC. The chamber was then emptied and recharged with 2.900 g of glucose (MW = 180.16 g/mol) and excess oxygen. How much did the temperature change from the combustion of the glucose? ΔHcomb for glucose is 2,780 kJ/mol.
Chemistry
1 answer:
torisob [31]3 years ago
6 0

Answer:

The temperature change from the combustion of the glucose is 6.097°C.

Explanation:

Benzoic acid;

Enthaply of combustion of benzoic acid = 3,228 kJ/mol

Mass of benzoic acid = 0.570 g

Moles of benzoic acid = \frac{0.570 g}{122.12 g/mol}=0.004667 mol

Energy released by 0.004667 moles of benzoic acid on combustion:

Q=3,228 kJ/mol \times 0.004667 mol=15.0668 kJ=15,066.8 J

Heat capacity of the calorimeter = C

Change in temperature of the calorimeter = ΔT = 2.053°C

Q=C\times \Delta T

15,066.8 J=C\times 2.053^oC

C=7,338.92 J/^oC

Glucose:

Enthaply of combustion of glucose= 2,780 kJ/mol.

Mass of glucose=2.900 g

Moles of glucose = \frac{2.900 g}{180.16 g/mol}=0.016097 mol

Energy released by the 0.016097 moles of calorimeter  combustion:

Q'=2,780 kJ/mol \times 0.016097 mol=44.7491 kJ=44,749.1 J

Heat capacity of the calorimeter = C (calculated above)

Change in temperature of the calorimeter on combustion of glucose = ΔT'

Q'=C\times \Delta T'

44,749.1 J=7,338.92 J/^oC\times \Delta T'

\Delta T'=6.097^oC

The temperature change from the combustion of the glucose is 6.097°C.

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