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Snezhnost [94]
3 years ago
7

Sulfuric acid (H2SO4) is prepared commercially from elemental sulfur using the contact process. In a typical sequence of reactio

ns, the sulfur is first burned: S + O2 → SO2 , then it is converted to SO3 using a catalyst: 2 SO2 + O2 → 2 SO3 . The resulting SO3 is reacted with water to produce the desired product: SO3 + H2O → H2SO4 . How much sulfuric acid could be prepared from 83 moles of sulfur? Answer in units of g.
Chemistry
2 answers:
Elan Coil [88]3 years ago
8 0
I believe the end result is still 83 moles since there is never an amount of sulfur atoms added to the initial amount, but rather oxygen and water is repeatedly added to it. To find it's weight, first find the molar mass of H2SO4:

H2 + S + O4 = 2.00 + 32.1 + 64.0 = 98.1 g/mol

and mass = (98.1 g/mol)(83 mol) = 8142.3 g

rounded to 8.1 x 10^3 g assuming 100% yield?
saveliy_v [14]3 years ago
6 0

Answer:

8134gH_{2}SO_{4}

Explanation:

From the first reaction:

S+O_{2}=SO_{2}

Finding the number of moles using stoichiometry:

83molesS*\frac{1molSO_{2}}{1molS}=83molesSO_{2}

Using stoichiometry in the second reaction:

_{2}SO_{2}+O_{2}=_{2}SO_{3}

83molesSO_{2}*\frac{2molesSO_{3}}{2molesSO_{2}}=83molesSO_{3}

From the third reaction:

SO_{3}+H_{2}O=H_{2}SO_{4}

83molesSO_{3}*\frac{1molH_{2}SO_{4}}{1molSO_{3}}=83molesH_{2}SO_{4}

Finding the mass in grams of H_{2}SO_{4}:

83molesH_{2}SO_{4}*\frac{98gH_{2}SO_{4}}{1molH_{2}SO_{4}}=8134gH_{2}SO_{4}

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Calculate the standard enthalpy of formation of NOCl(g) at 25 ºC, knowing that the standard enthalpy of formation of NO(g) at th
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Answer:

The standard enthalpy of formation of NOCl(g) at 25 ºC is 105 kJ/mol

Explanation:

The ∆H (heat of reaction) of the combustion reaction is the heat that accompanies the entire reaction. For its calculation you must make the total sum of all the heats of the products and of the reagents affected by their stoichiometric coefficient (number of molecules of each compound that participates in the reaction) and finally subtract them:

Enthalpy of the reaction= ΔH = ∑Hproducts - ∑Hreactants

In this case, you have:  2 NOCl(g) → 2 NO(g) + Cl₂(g)

So, ΔH=2*H_{NO} +H_{Cl_{2} }-2*H_{NOCl}

Knowing:

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Replacing:

75.5 kJ/mol=2* 90.25 kJ/mol + 0 - H_{NOCl}

Solving

-H_{NOCl}=75.5 kJ/mol - 2*90.25 kJ/mol

-H_{NOCl}=-105 kJ/mol

H_{NOCl}=105 kJ/mol

<u><em>The standard enthalpy of formation of NOCl(g) at 25 ºC is 105 kJ/mol</em></u>

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a) galvanic cell

b)electrolytic cell

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ii) K=3.58x10'-34

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d) E°=0.278 v

ΔG°= -26827 J

Explanation:

a) There are two kinds of an electrochemical cell, the first is called "galvanic cells", and the second "electrolytic cell".

The fuel cells are capable of produce electric energy through chemical reactions. These reactions are often spontaneous. So, the galvanic cell has a negative value for Gibbs free energy.

b) The electrolytic cell increases the value of Gibbs energy, to positive values, due to the reactions are not spontaneous.

c) i) look image attached

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ΔG° =-191070

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