Treatment of 1 mole of dimethyl sulfate with 2 moles of sodium acetylide results in the formation of propyne as the major produc
t.
A) Draw a reasonable mechanism accounting for the formation of the byproduct 2-butyne.
B) 2-Butyne is observed as a minor product of this reaction. Draw a mechanism accounting for the formation of this minor product and explain how your proposed mechanism is consistent with the observation that acetylene is present among the reaction products.
C) Predict the major and minor products that are expected if diethyl sulfate is used in place of dimethyl sulfate.
A) Draw a reasonable mechanism accounting for the formation of the byproduct 2-butyne.
B) 2-Butyne is observed as a minor product of this reaction. Draw a mechanism accounting for the formation of this minor product and explain how your proposed mechanism is consistent with the observation that acetylene is present among the reaction products.
C) Predict the major and minor products that are expected if diethyl sulfate is used in place of dimethyl sulfate.
1 answer:
Answer:
(a) appended underneath is the inorganic ion shaped in the reaction and the mechanism of its formation
(b) 2-butyne framed as a minor product is appeared in the connection. It is shaped when the monosodium subordinate of dimethylsulphoxide gets a hydrogen from the propyne and reacts again with monosodium methylsulphoxide.
(c) The major product framed when diethylsulphoxide is utilized, would be butyne and minor product would be 3-hexyne.
Explanation:
attached below is diagram
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Answer:
Elemental gold to have a Face-centered cubic structure.
Explanation:
From the information given:
Radius of gold = 144 pm
Its density = 19.32 g/cm³
Assuming the structure is a face-centered cubic structure, we can determine the density of the crystal by using the following:
a = 407 pm
In a unit cell, Volume (V) = a³
V = (407 pm)³
V = 6.74 × 10⁷ pm³
V = 6.74 × 10⁻²³ cm³
Recall that:
Net no. of an atom in an FCC unit cell = 4
Thus;
density d = 19.41 g/cm³
Similarly; For a body-centered cubic structure
where;
r = 144
a = 332.56 pm
In a unit cell, Volume V = a³
V = (332.56 pm)³
V = 3.68 × 10⁷ pm³
V 3.68 × 10⁻²³ cm³
Recall that:
Net no. of atoms in BCC cell = 2
∴
density =17.78 g/cm³
From the two calculate densities, we will realize that the density in the face-centered cubic structure is closer to the given density.
This makes the elemental gold to have a Face-centered cubic structure.