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Lyrx [107]
3 years ago
9

The smell of fresh cut pine is due in part to the cyclic alkene called pinene. Given the following data of pinene: Vapor pressur

e (torr) Temperature (K) 760 429 515 415 Calculate the heat of vaporization, ΔHvap, of pinene.
Chemistry
1 answer:
Sveta_85 [38]3 years ago
4 0

Answer: Heat of vaporization is 41094 Joules

Explanation:

The vapor pressure is determined by Clausius Clapeyron equation:

ln(\frac{P_2}{P_1})=\frac{\Delta H_{vap}}{R}(\frac{1}{T_1}-\frac{1}{T_2})

where,

P_1= initial pressure at  429 K = 760 torr

P_2 = final pressure at 415 K  = 515 torr

= enthalpy of vaporisation = ?

R = gas constant = 8.314 J/mole.K

T_1= initial temperature =  429 K

T_2 = final temperature = 515 K

Now put all the given values in this formula, we get

\log (\frac{515}{760}=\frac{\Delta H}{2.303\times 8.314J/mole.K}[\frac{1}{429K}-\frac{1}{415K}]

\Delta H=41094J

Thus the heat of vaporization is 41094 Joules

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Answer:

A. Students made a measurement error, because ending with more products is impossible.

Explanation:

The law of conversation of matter tells us that in a chemical reaction, matter is never created or destroyed, it's simply converted from one form to another. So the mass of reactants should always equal the mass of the products in a chemical reaction. If there is excess mass in the product, the students have made an error of some kind.

4 0
3 years ago
For the reaction 2 H2S(g) D 2 H2 (g) + S2 (g), Kp = 1.5 × 10−5 at 800.0°C. If the initial partial pressures of H2 and S2 in a cl
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Explanation:

Equilibrium constant is the ratio of the concentration of products to the concentration of reactants each term raised to its stochiometric coefficients.

The given balanced equilibrium reaction is,

      2H_2S(g)\rightleftharpoons 2H_2(g)+S_2(g)

K_p=\frac{[H_2]^2\times [S_2]}{[H_2S]^2}

1.5\times 10^{-5}=\frac{[H_2]^2\times [S_2]}{[H_2S]^2}

On reversing the reaction:

     2H_2(g)+S_2(g)\rightleftharpoons 2H_2S(g)

initial pressure  4.00atm    2.00 atm       0

eqm          (4.00-2x)atm      (2.00-x) atm      2x atm

K_p=\frac{[H_2S]^2}{[H_2]^2\times [S_2]}

K_p'=\frac{1}{K_p}=0.67\times 10^5

2H_2(g)+S_2(g)\rightleftharpoons 2H_2S(g)

0.67\times 10^5=\frac{2x]^2}{[4.00-2x]^2\times [2.00-x]}

x=1.96

[H_2S]=2x=2\times 1.96=3.92 atm

Thus approximate equilibrium partial pressure of H_2S is 3.92 atm

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