Answer:
D
Explanation:
the answer is d white precipitate
Answer:
Article is
I was born in <em><u>t</u></em><em><u>h</u></em><em><u>e</u></em><em><u> </u></em> west .
Answer:
15.2 mL
Explanation:
First we calculate the volume of the copper
when this volume of copper is added to the water, the water level will rise by the level of the volume of copper. So the final volume is:
14.6 mL + 0.5580 mL = 15.158 mL
Since the measuring cylinder is graduated to one decimal place , we can round this up to 15.2 mL
a) After adding 10 mL of HCl
first, we need to get moles of (CH3)3N = molarity * volume
= 0.29 m * 0.025 L
= 0.00725M moles
then, we need to get moles of HCl = molarity * volume
= 0.3625 m * 0.01L
= 0.003625 moles
so moles of (CH3)3N remaining = moles of (CH3)3N - moles of HCl
= 0.00725 - 0.003625
= 0.003625 moles
and when the total volume = 0.01 L + 0.025L = 0.035 L
∴ [(CH3)3N] = moles remaining / total volume
= 0.003625 moles / 0.035L
= 0.104 M
when we have Pkb so we can get Kb :
pKb = - ㏒Kb
4.19 = -㏒Kb
∴Kb = 6.5 x 10^-5
when Kb = [(CH3)3NH+] [OH-] / [(CH3)3N]
and by using ICE table we assume we have:
[(CH3)3NH+] = X & [OH] = X
and [(CH3)3N] = 0.104 -X
by substitution:
∴ 6.5 x 10^-5 = X^2 / (0.104-X) by solving for X
∴X = 0.00257 M
∴[OH-] = X = 0.00257 M
∴POH = -㏒[OH]
= -㏒0.00257
= 2.5
∴ PH = 14 - POH
= 14 - 2.5
= 11.5
b) after adding 20ML of HCL:
moles of HCl = molarity * volume
= 0.3625 m * 0.02 L
= 0.00725 moles
the complete neutralizes of (CH3)3N we make 0.003625 moles of (CH3)3NH+ So, now we need the Ka value of (CH3)3NH+:
and when the total volume = 0.02L + 0.025 = 0.045L
∴ [ (CH3)3NH+] = moles / total volume
= 0.003625 / 0.045L
= 0.08 M
when Ka = Kw / Kb
and we have Kb = 6.5 x 10^-5 & we know that Kw = 1 x 10^-14
so, by substitution:
Ka = (1 x 10^-14) / (6.5 x 10^-5)
= 1.5 x 10^-10
when Ka expression = [(CH3)3N][H+] / [(CH3)3NH+]
by substitution:
∴ 1.5 x 10^-10 = X^2 / (0.08 - X) by solving for X
∴X = 3.5 x 10^-6 M
∴ [H+]= X = 3.5 x 10^-6 M
∴PH = -㏒[H+]
= -㏒(3.5 x 10^-6)
= 5.5
C) after adding 30ML of HCl:
moles of HCl = molarity * volume
= 0.3625m * 0.03L
= 0.011 moles
and when moles of (CH3)3N neutralized = 0.003625 moles
∴ moles of HCl remaining = moles HCl - moles (CH3)3N neutralized
= 0.011moles - 0.003625moles
= 0.007375 moles
when total volume = 0.025L + 0.03L
= 0.055L
∴[H+] = moles / total volume
= 0.007375 mol / 0.055L
= 0.134 M
∴PH = -㏒[H+]
= -㏒ 0.134
= 0.87
