Answer:
2.53 L is the volume of H₂ needed
Explanation:
The reaction is: C₁₈H₃₀O₂ + 3H₂ → C₁₈H₃₆O₂
By the way we can say, that 1 mol of linolenic acid reacts with 3 moles of oxygen in order to produce, 1 mol of stearic acid.
By stoichiometry, ratio is 1:3
Let's convert the mass of the linolenic acid to moles:
10.5 g . 1 mol / 278.42 g = 0.0377 moles
We apply a rule of three:
1 mol of linolenic acid needs 3 moles of H₂ to react
Then, 0.0377 moles will react with (0.0377 . 3 )/1 = 0.113 moles of hydrogen
We apply the Ideal Gases Law to find out the volume (condition of measure are STP) → P . V = n . R . T → V = ( n . R .T ) / P
V = (0.113 mol . 0.082 L.atm/mol.K . 273.15K) 1 atm = 2.53 L
use a strong base to neutralize, like NaOH, KOH, etc
Answer:
-88.66 kJ/mol
Explanation:
The expressions of heat capacity (Cp,m) for C(s) and for H₂(g) are:
C(s): Cp,m/(J K-1 mol-1) = 16.86 + (4.77T/10³) - (8.54x10⁵/T²)
H₂(g): Cp,m/(J K-1 mol-1) = 27.28 + (3.26T/10³) + (0.50x10⁵/T²)
Cp = A + BT + CT⁻²
For the Kirchoff's Law:
ΔHf = ΔH°f + 
Where ΔH°f is the enthalpy at 298 K, T1 is 298 K, T2 is the temperature given (373 K), and DCp is the variation of Cp (products less reactants). ΔH°f for ethene is -84.68 kJ/mol and the reaction is:
2C(s) + 3H₂(g) → C₂H₆
So, DCp:
dA = A(C₂H₆) - [2xA(C) + 3xA(H₂)] = 14.73 - [2x16.86 + 3x27.28] = -100.83
dB = B(C₂H₆) - [2xB(C) + 3xB(H₂)] = 0.1272 - [2x4.77x10⁻³ + 3x3.26x10⁻³] = 0.10788
dC = C(C₂H₆) - [2xC(C) + 3xC(H₂)] = 0 - (2x(-8.54x10⁵) + 3x0.50x10⁵) = 15.58x10⁵
dCp = -100.83 + 0.10788T + 15.58x10⁵T⁻²
= -3796.48 J/mol = -3.80 kJ/mol (solved by a graphic calculator)
ΔHf = -84.68 - 3.80
ΔHf = -88.66 kJ/mol