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3 years ago

What is the reaction quotient, Q, for this system when [N2] = 2.00 M, [H2] = 2.00 M, and [NH3] = 1.00 M at 472°C?

Chemistry

1 answer:

cupoosta [38]3 years ago

3 0

Answer : The value of reaction quotient, Q is 0.0625.

Solution : Given,

Concentration of $N_2$ = 2.00 M

Concentration of $H_2$ = 2.00 M

Concentration of $NH_3$ = 1.00 M

Reaction quotient : It is defined as a concentration of a chemical species involved in the chemical reaction.

The balanced equilibrium reaction is,

$N_2+3H_2\rightleftharpoons 2NH_3$

The expression of reaction quotient for this reaction is,

$Q=\frac{[Product]^p}{[Reactant]^r}\\Q=\frac{[NH_3]^2}{[N_2]^1[H_2]^3}$

Now put all the given values in this expression, we get

$Q=\frac{(1.00)^2}{(2.00)^1(2.00)^3}=0.0625$

Therefore, the value of reaction quotient, Q is 0.0625.

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Calculate the wavelength of light emitted when each of the following transitions occur in the hydrogen atom. What type of electr

Alecsey [184]

Answer:

The wavelength of the emitted photon will be approximately 655 nm, which corresponds to the visible spectrum.

Explanation:

In order to answer this question, we need to recall Bohr's formula for the energy of each of the orbitals in the hydrogen atom:

$E_{n} = -\frac{m_{e}e^{4}}{2(4\pi\epsilon_{0})^2\hbar^{2}}\frac{1}{n^2} = E_{1}\frac{1}{n^{2}}$ , where:

[tex]m_{e}[tex] = electron mass

e = electron charge

[tex]\epsilon_{0}[tex] = vacuum permittivity

[tex]\hbar[tex] = Planck's constant over 2pi

n = quantum number

[tex]E_{1}[tex] = hydrogen's ground state = -13.6 eV

Therefore, the energy of the emitted photon is given by the difference of the energy in the 3d orbital minus the energy in the 2nd orbital:

[tex]E_{3} - E_{2} = -13.6 eV(\frac{1}{3^{2}} - \frac{1}{2^{2}})=1.89 eV[tex]

Now, knowing the energy of the photon, we can calculate its wavelength using the equation:

[tex]E = \frac{hc}{\lambda}[tex], where:

E = Photon's energy

h = Planck's constant

c = speed of light in vacuum

[tex]\lambda[tex] = wavelength

Solving for [tex]\lambda[tex] and substituting the required values:

[tex]\lambda = \frac{hc}{E} = \frac{1.239 eV\mu m}{1.89 eV}=0.655\mu m = 655 nm[tex], which correspond to the visible spectrum (The visible spectrum includes wavelengths between 400 nm and 750 nm).

5 0

3 years ago

I NEED HELP PLEASE, THANKS!

Liono4ka [1.6K]

Just need some point sorry

3 0

3 years ago

Determine Z and V for steam at 250°C and 1800 kPa by the following: (a) The truncated virial equation [Eq. (3.38)] with the foll

makvit [3.9K]

Answer:

Explanation:

Given that:

the temperature $T_1$ = 250 °C= ( 250+ 273.15 ) K = 523.15 K

Pressure = 1800 kPa

The truncated viral equation is expressed as:

$\frac{PV}{RT} = 1 + \frac{B}{V} + \frac{C}{V^2}$

where; B = - $152.5 \ cm^3 /mol$ C = -5800 $cm^6/mol^2$

R = 8.314 × 10³ cm³ kPa. K⁻¹.mol⁻¹

Plugging all our values; we have

$\frac{1800*V}{8.314*10^3*523.15} = 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

$4.138*10^{-4} \ V= 1+ \frac{-152.5}{V} + \frac{-5800}{V^2}$

Multiplying through with V² ; we have

$4.138*10^4 \ V ^3 = V^2 - 152.5 V - 5800 = 0$

$4.138*10^4 \ V ^3 - V^2 + 152.5 V + 5800 = 0$

V = 2250.06 cm³ mol⁻¹

Z = $\frac{PV}{RT}$

Z = $\frac{1800*2250.06}{8.314*10^3*523.15}$

Z = 0.931

b) The truncated virial equation [Eq. (3.36)], with a value of B from the generalized Pitzer correlation [Eqs. (3.58)–(3.62)].

The generalized Pitzer correlation is :

$T_c = 647.1 \ K \\ \\ P_c = 22055 \ kPa \\ \\ \omega = 0.345$

$T__{\gamma}} = \frac{T}{T_c}$

$T__{\gamma}} = \frac{523.15}{647.1}$

$T__{\gamma}} = 0.808$

$P__{\gamma}} = \frac{P}{P_c}$

$P__{\gamma}} = \frac{1800}{22055}$

$P__{\gamma}} = 0.0816$

$B_o = 0.083 - \frac{0.422}{T__{\gamma}}^{1.6}}$

$B_o = 0.083 - \frac{0.422}{0.808^{1.6}}$

$B_o = 0.51$

$B_1 = 0.139 - \frac{0.172}{T__{\gamma}}^{ \ 4.2}}$

$B_1 = -0.282$

The compressibility is calculated as:

$Z = 1+ (B_o + \omega B_1 ) \frac{P__{\gamma}}{T__{\gamma}}$

$Z = 1+ (-0.51 +(0.345* - 0.282) ) \frac{0.0816}{0.808}$

Z = 0.9386

$V= \frac{ZRT}{P}$

$V= \frac{0.9386*8.314*10^3*523.15}{1800}$

V = 2268.01 cm³ mol⁻¹

c) From the steam tables (App. E).

At $T_1 = 523.15 \ K \ and \ P = 1800 \ k Pa$

V = 0.1249 m³/ kg

M (molecular weight) = 18.015 gm/mol

V = 0.1249 × 10³ × 18.015

V = 2250.07 cm³/mol⁻¹

R = 729.77 J/kg.K

Z = $\frac{PV}{RT}$

Z = $\frac{1800*10^3 *0.1249}{729.77*523.15}$

Z = 0.588

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How does the tendency of iron to rust depend on ph?

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