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Anna71 [15]
3 years ago
14

A fuel cell designed to react grain alcohol with oxygen has the following net reaction:

Chemistry
1 answer:
sertanlavr [38]3 years ago
8 0

Answer:

b. E = 2,28V

Explanation:

The maximum work is the same than ΔG. As ΔG could be written as:

ΔG = nFE <em>(1)</em>

Where n is moles of electrons transferred, F is faraday constant (96485 J/Vmol) and E is the voltage of the cell.

For the reaction:

CH₃OH(l) + ³/₂O₂(g) → CO₂(g) + 2H₂O(l)

The oxidation state of C in CH₃OH is -2 but in CO₂ is +4, that means transferred electrons are +4 - -2 = <em>6e⁻</em>

Replacing in (1):

1320x10³ J = 6mol e⁻×96485J/Vmol×E

<em>E = 2,28V</em>

<em></em>

I hope it helps!

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Calculate E ° for the half‑reaction, AgCl ( s ) + e − − ⇀ ↽ − Ag ( s ) + Cl − ( aq ) given that the solubility product constant
antoniya [11.8K]

Answer: The value of E^{o} for the half-cell reaction is 0.222 V.

Explanation:

Equation for solubility equilibrium is as follows.

          AgCl(s) \rightleftharpoons Ag^{+}(aq) + Cl^{-}(aq)

Its solubility product will be as follows.

       K_{sp} = [Ag^{+}][Cl^{-}]

Cell reaction for this equation is as follows.

     Ag(s)| AgCl(s)|Cl^{-}(0.1 M)|| Ag^{+}(1.0 M)| Ag(s)

Reduction half-reaction: Ag^{+} + 1e^{-} \rightarrow Ag(s),  E^{o}_{Ag^{+}/Ag} = 0.799 V

Oxidation half-reaction: Ag(s) + Cl^{-}(aq) \rightarrow AgCl(s) + 1e^{-},   E^{o}_{AgCl/Ag} = ?

Cell reaction: Ag^{+}(aq) + Cl^{-}(aq) \rightarrow AgCl(s)

So, for this cell reaction the number of moles of electrons transferred are n = 1.

    Solubility product, K_{sp} = [Ag^{+}][Cl^{-}]

                                               = 1.77 \times 10^{-10}

Therefore, according to the Nernst equation

           E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

At equilibrium, E_{cell} = 0.00 V

Putting the given values into the above formula as follows.

         E_{cell} = E^{o}_{cell} - \frac{0.0592 V}{n} log \frac{[AgCl]}{[Ag^{+}][Cl^{-}]}

        0.00 = E^{o}_{cell} - \frac{0.0592 V}{1} log \frac{1}{[Ag^{+}][Cl^{-}]}    

       E^{o}_{cell} = \frac{0.0592}{1} log \frac{1}{K_{sp}}

                  = 0.0591 V \times log \frac{1}{1.77 \times 10^{-10}}

                  = 0.577 V

Hence, we will calculate the standard cell potential as follows.

           E^{o}_{cell} = E^{o}_{cathode} - E^{o}_{anode}

       0.577 V = E^{o}_{Ag^{+}/Ag} - E^{o}_{AgCl/Ag}

       0.577 V = 0.799 V - E^{o}_{AgCl/Ag}

       E^{o}_{AgCl/Ag} = 0.222 V

Thus, we can conclude that value of E^{o} for the half-cell reaction is 0.222 V.

3 0
3 years ago
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<span>By the way, the answer you're looking for is "Because Group I cations have insoluble chlorides". </span>

<span>"In order...to distinguish cation Group I, one adds HCl to a sample. If a Group I cation is present in the sample, a precipitate will form." </span>
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