Determine the volume at STP of 36.8 g of nitrogen dioxide(NO2)

At 25∘C, the decomposition of dinitrogen pentoxide, N2O5(g), into NO2(g) and O2(g) follows first-order kinetics with k=3.4×10−5

Annette [7]

Answer:

4600s

Explanation:

$2N_{2}O_{5}(g) - - -> 4NO_{2}(g) +O_{2}$

For a first order reaction the rate of reaction just depends on the concentration of one specie [B] and it’s expressed as:

$-\frac{d[B]}{dt}=k[B] - - - -\frac{d[B]}{[B]}=k*dt$

If we have an ideal gas in an isothermal (T=constant) and isocoric (v=constant) process.

PV=nRT we can say that P = n so we can express the reaction order as a function of the Partial pressure of one component.

$-\frac{d[P(B)]}{P(B)}=k*dt$

$-\frac{d[P(N_{2}O_{5})]}{P(N_{2}O_{5})}=k*dt$

Integrating we get:

$\int\limits^p \,-\frac{d[P(N_{2}O_{5})]}{P(N_{2}O_{5})}=\int\limits^ t k*dt$

$-(ln[P(N_{2}O_{5})]-ln[P(N_{2}O_{5})_{o})])=k(t_{2}-t_{1})$

Clearing for t2:

$\frac{-(ln[P(N_{2}O_{5})]-ln[P(N_{2}O_{5})_{o})])}{k}+t_{1}=t_{2}$

$ln[P(N_{2}O_{5})]=ln(650)=6.4769$

$ln[P(N_{2}O_{5})_{o}]=ln(760)=6.6333$

$t_{2}=\frac{-(6.4769-6.6333)}{3.4*10^{-5}}+0= 4598.414s$

4 0

3 years ago

PLEASE HELP ME ASAP THIS IS DUE IN 10 MINUTES AND I AM STUCK!!

Art [367]

Answer:

c

Explanation:

8 0

2 years ago

Read 2 more answers

A gaseous substance turns into a solid. Which best describes this change? A substance that has a specific shape changes to a sub

Snezhnost [94]

A substance that has no specific volume changes to a substance that has a specific volume.

8 0

3 years ago

Read 2 more answers

What is true if a liquid and a gas are in equilibrium?

MAXImum [283]

Answer:

A - Liquid molecules forming a gas and gas molecules forming a

liquid are equal in number.

Explanation:

A P E X

6 0

3 years ago

When 100 mL of 0.200 M NaCl(aq) and 100 mL of 0.200 M AgNO3(aq), both at 21.9 °C, are mixed in a coffee cup calorimeter, the tem

masya89 [10]

Answer:

There is 1.3 kJ heat produced(released)

Explanation:

Step 1: Data given

Volume of a 0.200 M Nacl solution = 100 mL = 0.1 L

Volume of a 0.200 M AgNO3 solution = 100 mL = 0.1 L

Initial temperature = 21.9 °C

Final temperature = 23.5 °C

Solid AgCl will be formed

Step 2: The balanced equation:

AgNO3(aq) + NaCl(aq) → AgCl(s) + NaNO3(aq)

AgCl(s) + NaNO3(aq) → Na+(aq) + NO3-(aq) + AgCl(s)

Step 3: Define the formula

Pressure is constant. → the heat evolved from the reaction is equivalent to the enthalpy of reaction.

Q=m*c*ΔT

⇒ Q = the heat transfer (in joule)

⇒ m =the mass (in grams)

⇒ c= the heat capacity (J/g°C)

⇒ ΔT = Change in temperature = T2- T1

Step 4: Calculate heat

Let's vonsider the density the same as the density of water (1g/mL)

Mass = volume * density

Mass = 200 mL * 1g/mL

Mass = 200 grams

Q= m*c*ΔT

⇒ m = 200 grams

⇒ c = the heat capacity (let's consider the heat capacity of water) = 4.184 J/g°C

⇒ ΔT = 23.5 -21.9 = 1.6°C

Q = 200 * 4.184 * 1.6 = 1338 .9 J = 1.3 kJ

There is 1.3 kJ heat produced(released)

Therefore, we assumed no heat is absorbed by the calorimeter, no heat is exchanged between the calorimeter and its surroundings, and the specific heat and mass of the solution are the same as those for water (1g/mL and 4.184 J/g°C)

7 0

3 years ago