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H3PO4 has molecular weight of approximately 98 grams per
mole. 4.50 M is equal to 4.50 mole per 1000 mL solution of H3PO4. 255 mL times
4.50 mol /1000 mL times 98 g/mol is equal to 112.455 grams. Note that I
automatically equate 1 Liter to 1000 mL since the given volume is in mL for
easier computation.
Answer:
Option b. Decomposition
Followed by a reduction process using charcoal
Explanation:
Lead can be obtained from lead nitrate by thermal decomposition of lead nitrate as shown below:
2Pb(NO3)2 —> 2PbO + 4NO2 + O2
The PbO obtained is reduced by charcoal(C) to obtain the metallic Pb as shown below:
2PbO + C —> Pb + CO2
The number of moles of gas lost is 0.0213 mol. It can be solved with the help of Ideal gas law.
<h3>What is Ideal law ?</h3>
According to this law, "the volume of a given amount of gas is directly proportional to the number on moles of gas, directly proportional to the temperature and inversely proportional to the pressure. i.e.
PV = nRT.
Where,
- p = pressure
- V = volume (1.75 L = 1.75 x 10⁻³ m³)
- T = absolute temperature
- n = number of moles
- R = gas constant, 8.314 J*(mol-K)
Therefore, the number of moles is
n = PV / RT
State 1 :
- T₁ = (25⁰ C = 25+273 = 298 K)
- p₁ = 225 kPa = 225 x 10³ N/m²
State 2 :
- T₂ = 10 C = 283 K
- p₂ = 185 kPa = 185 x 10³ N/m²
The loss in moles of gas from state 1 to state 2 is
Δn = V/R (P₁/T₁ - P₂/T₂ )
V/R = (1.75 x 10⁻³ m³)/(8.314 (N-m)/(mol-K) = 2.1049 x 10⁻⁴ (mol-m²-K)/N
p₁/T₁ = (225 x 10³)/298 = 755.0336 N/(m²-K)
p₂/T₂ = (185 x 10³)/283 = 653.7102 N/(m²-K)
Therefore,
Δn = (2.1049 x 10⁻⁴ (mol-m²-K)/N)*(755.0336 - 653.7102 N/(m²-K))
= 0.0213 mol
Hence, The number of moles of gas lost is 0.0213 mol.
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