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Lapatulllka [165]
4 years ago
11

Calculate the ΔG for the following system. Then state if the system is spontaneous or not spontaneous. ΔH = 147 kJ ΔS = -67.0 J/

K T = 149 °C
Chemistry
1 answer:
lbvjy [14]4 years ago
5 0

Answer:

ΔG for the given system is 28.421 kJ. The system is non spontaneous.

Explanation:

ΔH = 147 kJ =147,000 J= Enthalpy of the system

ΔS = -67.0 J/K = Entropy change

T = 149 °C = 422.15 K = Temperature of the system

((T)°C=273.15 +T K)

ΔG = Gibbs free energy ?

The Gibbs free energy 's expression is given by:

ΔG = ΔH  - T ΔS

  • ΔG > 0 , non spontaneous
  • ΔG < 0, spontaneous

\Delta G^o=147,000 J-422.15 K\times (-67.0)

ΔG = 28,421 J = 28.421 kJ

Since, value of Gibbs free energy is positive this means that reaction is non spontaneous.

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Question:

A chemistry student needs of 10 g isopropenylbenzene for an experiment. He has available 120 g of a 42.7% w/w solution of isopropenylbenzene in acetone. Calculate the mass of solution the student should use. If there's not enough solution, press the "No solution" button.

Answer:

The answer to the question is as follows

The mass of solution the student should use is 23.42 g.

Explanation:

To solve the question we note the following

A solution containing 42.7 % w/w of isopropenylbenzene in acetone  has 42.7 g of isopropenylbenzene in 100 grams of the solution

Therefore we have 10 g of isopropenylbenzene contained in

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Therefore the quantity to used from the available solution = 23.42 g of the isopropenylbenzene in acetone solution.

8 0
4 years ago
A compound is found to contain 73.23% xenon name 26.77% oxygen by mass. What is the empirical formula for this compound ?
Luba_88 [7]

The empirical formula is XeO₃.

<u>Explanation:</u>

Assume 100 g of the compound is present. This changes the percents to grams:

Given mass in g:

Xenon = 73.23 g

Oxygen = 26.77 g

We have to convert it to moles.

Xe = 73.23/   131.293 = 0.56 moles

O = 26.77/ 16 = 1.67 moles

Divide by the lowest value, seeking the smallest whole-number ratio:

Xe = 0.56/ 0.56 = 1

O = 1.67/ 0.56 = 2.9 ≈3

So the empirical formula is XeO₃.

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3 years ago
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Consider two concentric spheres whose radii differ by t = 1 nm, the "thickness" of the interface. At what radius (in nm) of sphe
Gala2k [10]

Answer:

Radius of the interior sphere = 3.847 nm

Explanation:

The volume of the shell (Vs) is equal to the difference of the volume of the outer sphere (Vo) and the volume of the inner sphere (Vi). Then:

V_s=V_o-V_i=V_i\\V_o=2*V_i\\

If we express the radius of the outer sphere (ro) in function of the radius of the inner sphere (ri), we have (e being the shell thickness):

r_o=r_i+e

The first equation becomes

\frac{4 \pi}{3}*r_o^{3}  = 2 * \frac{4 \pi}{3}*r_i^{3}  \\\\\frac{4 \pi}{3}*(r_i+e)^{3}  = 2 * \frac{4 \pi}{3}*r_i^{3}  \\\\(r_i+e)^{3}  = 2 *r_i^{3}  \\\\(r_i^{3}+3r_i^{2}e+3r_ie^{2}+e^{3})=2r_i^{3}\\\\-r_i^{3}+3r_i^{2}e+3r_ie^{2}+e^{3}=0\\\\-r_i^{3}+3r_i^{2}+3r_i+1=0

To find ri that satisfies this equation we have to find the roots of the polynomial.

Numerically, it could be calculated that ri=3.847 nm satisfies the equation.

So if the radius of the interior sphere is 3.847 nm, the volume of the interior sphere is equal to the volume of the shell of 1nm.

8 0
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