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shusha [124]
3 years ago
5

A silver block, initially at 58.5°C, is submerged into 100.0 of water at 24.8°C in an insulated container. The final temperature

of the mixture upon reaching thermal equilibrium is 26.2 °C. What is the mass of the silver block?
Chemistry
1 answer:
Lady bird [3.3K]3 years ago
5 0

Answer:

77.6 g are the mass of silver

Explanation:

This is a calorimetry problem, All the heat released by the silver was gained by the water, so the T° has increased.

Q = m . C . ΔT

mass from silver . 0.056 cal/g°C . (26.2°C - 58.5°C) = 100 g . 1 cal/g°C (26.2°C - 24.8°C)

mass from silver . 0.056 cal/g°C .-32.3°C = 100 g . 1 cal/g°C . 1.4°C

mass from silver . -1.8032 cal/g = 140 cal

mass from silver = 140 cal / 1.8032 g/cal

mass from silver = 77.6 g

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C₄H₈O₂               -------->            C₄H₇O₂⁻          +           H⁺

I                    0.54x10⁻³                             0                                0

E                   0.54x10⁻³(1-x)                      0.54x10⁻³x                0.54x10⁻³x

Recall that x is the percentage degree of dissociation

From the ICE table;

Ka = [C₄H₇O₂⁻] [ H⁺]/[C₄H₈O₂]

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1.51x10⁻⁵ = 0.54x10⁻³x^2/1-x

1.51x10⁻⁵(1-x) = 0.54x10⁻³x^2

1.51x10⁻⁵ - 1.51x10⁻⁵x = 0.54x10⁻³x^2

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Ignoring the negative result, x = 0.154

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