Because if they are not balanced, then the amount of reaction is not equal to the amount of the product. You must have the same ratio of atoms on both sides of the equation because we are not losing moles of each element.
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<span>0.0165 m
The balanced equation for the reaction is
AgNO3 + MgCl2 ==> AgCl + Mg(NO3)2
So it's obvious that for each Mg ion, you'll get 1 AgCl molecule as a product. Now calculate the molar mass of AgCl, starting with looking up the atomic weights.
Atomic weight silver = 107.8682
Atomic weight chlorine = 35.453
Molar mass AgCl = 107.8682 + 35.453 = 143.3212 g/mol
Now how many moles were produced?
0.1183 g / 143.3212 g/mol = 0.000825419 mol
So we had 0.000825419 moles of MgCl2 in the sample of 50.0 ml. Since concentration is defined as moles per liter, do the division.
0.000825419 / 0.0500 = 0.016508374 mol/L = 0.016508374 m
Rounding to 3 significant figures gives 0.0165 m</span>