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inessss [21]
4 years ago
8

a 125 g chunk of aluminum at 182 degrees Celsius was added to a bucket filled with 365 g of water at 22.0 degrees Celsius. Ignor

ing the specific heat of the bucket, calculate the final temperature of the two compounds once thermal equilibrium is reached
Chemistry
1 answer:
Diano4ka-milaya [45]4 years ago
7 0
<h3>Answer:</h3>

32.98°C

<h3>Explanation:</h3>

We are given the following;

Mass of Aluminium as 125 g

Initial temperature of Aluminium as 182°C

Mass of water as 265 g

Initial temperature of water as 22°C

We are required to calculate the final temperature of the two compounds;

First, we need to know the specific heat capacity of each;

Specific heat capacity of Aluminium is 0.9 J/g°C

Specific heat capacity of water is 4.184 J/g°C

<h3>Step 1: Calculate the Quantity of heat gained by water.</h3>

Assuming the final temperature is X°C

we know, Q = mcΔT

Change in temperature, ΔT = (X-22)°C

therefore;

Q = 365 g × 4.184 J/g°C × (X-22)°C

    = (1527.16X-33,597.52) Joules

<h3>Step 2: Calculate the quantity of heat released by Aluminium </h3>

Using the final temperature, X°C

Change in temperature, ΔT = -(X°- 182°)C (negative because heat was lost)

Therefore;

Q = 125 g × 0.90 J/g°C × (182°-X°)C

  = (20,475- 112.5X) Joules

<h3>Step 3: Calculating the final temperature</h3>

We need to know that the heat released by aluminium is equal to heat absorbed by water.

Therefore;

(20,475- 112.5X) Joules = (1527.16X-33,597.52) Joules

Combining the like terms;

1639.66X = 54072.52

             X = 32.978°C

                = 32.98°C

Therefore, the final temperature of the two compounds will be 32.98°C

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Considering the Hess's Law, the enthalpy change for the reaction is -906.4 kJ/mol.

<h3>Hess's Law</h3>

Hess's Law indicates that the enthalpy change in a chemical reaction will be the same whether it occurs in a single stage or in several stages. That is, the sum of the ∆H of each stage of the reaction will give us a value equal to the ∆H of the reaction when it occurs in a single stage.

<h3>ΔH in this case</h3>

In this case you want to calculate the enthalpy change of:

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You know the following reactions, with their corresponding enthalpies:

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Equation 2:  2 N₂ + 2 O₂ → 4 NO     ΔH = 361.1 kJ/mol

Equation 3: 2 H₂ + O₂→ 2 H₂O     ΔH = -483.7 kJ/mol

Because of the way formation reactions are defined, any chemical reaction can be written as a combination of formation reactions, some going forward and some going back.

In this case, first, to obtain the enthalpy of the desired chemical reaction you need 4 moles of NH₃ on reactant side and it is present in first equation on product side. So you need to invert the reaction, and when an equation is inverted, the sign of delta H also changes.

Now, 4 moles of NO must be a product and is present in the second equation, so let's write this as such.

Finally, you need 6 moles of H₂O on the product side, so you need to multiply by 3 the third equation to obtain the amount of water that you need. Since enthalpy is an extensive property, that is, it depends on the amount of matter present, since the equation is multiply by 3, the variation of enthalpy also.

In summary, you know that three equations with their corresponding enthalpies are:

Equation 1: 2 4 NH₃ → N₂ + 6 H₂  ΔH = 183.6 kJ/mol

Equation 2:  2 N₂ + 2 O₂ → 4 NO     ΔH = 361.1 kJ/mol

Equation 3: 6 H₂ + 3 O₂→ 6 H₂O     ΔH = -1,451.1 kJ/mol

Adding or canceling the reactants and products as appropriate, and adding the enthalpies algebraically, you obtain:

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Learn more about Hess's law:

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brainly.com/question/6263007

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brainly.com/question/2912965

#SPJ1

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