Answer:
Number molecules present = 4.92 multipled by avogadro's number.
Answer:
<u>The deviations are :</u>
- <u>The activation energy which changes with temperature</u>
- <u>The arrhenius constant which depends on the temperature</u>
Explanation:
- There are deviations from the Arrhenius law during the glass transition in all classes of glass-forming matter.
- The Arrhenius law predicts that the motion of the structural units (atoms, molecules, ions, etc.) should slow down at a slower rate through the glass transition than is experimentally observed.
- In other words, the structural units slow down at a faster rate than is predicted by the Arrhenius law.
- <em>This observation is made reasonable assuming that the units must overcome an energy barrier by means of a thermal activation energy. </em>
- The thermal energy must be high enough to allow for translational motion of the units <em>which leads to viscous flow of the material.</em>
- Both the Arrhenius activation energy and the rate constant k are experimentally determined, and represent macroscopic reaction-specific parameters <em>that are not simply related to threshold energies and the success of individual collisions at the molecular level. </em>
- Consider a particular collision (an elementary reaction) between molecules A and B. The collision angle, the relative translational energy, the internal (particularly vibrational) energy will all determine the chance that the collision will produce a product molecule AB.
- Macroscopic measurements of E(activation energy) and k(rate constant ) <em>are the result of many individual collisions with differing collision parameters. </em><em>They are averaged out to a macroscopic quantity.</em>
<span>Zn⁰(s) + CuSO4(aq) --> Zn²⁺SO4²⁻(aq) + Cu(s)
</span>Zn⁰ --- in free elements oxidation number is 0.
Zn²⁺SO4²⁻ ---- ionic compound , it has ion Zn²⁺, so oxidation number here is +2.
<span>The oxidation number of Zn changes from 0 to +2.</span>
Using Daltons Law which states that the total pressure of a gas mixture is the sum of the gasses partial pressure.Thus,
Pt(total pressure)= P1+P2+P3
where
Pt= 0.90 atm
P1= 0.26 atm
P2 = 0.28 atm
P3 = ?
substitute the formula with known variables
P3= 0.90 atm-(0.26atm+0.28atm)
P3 = 0.36 atm
The partial pressure of ammonia is 0.36 atm