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butalik [34]
3 years ago
12

For elements in the third row of the periodic table and beyond, the octet rule is often not obeyed. a friend of yours says this

is because these heavier elements are more likely to make double or triple bonds. another friend of yours says that this is because the heavier elements are larger and can make bonds to more than four atoms at a time. part a which friend is most correct?
Chemistry
1 answer:
Rom4ik [11]3 years ago
4 0

The reason that some of the elements of period three and beyond are steady in spite of not sticking to the octet rule is due to the fact of possessing the tendency of forming large size, and a tendency of making more than four bonds. For example, sulfur, it belongs to period 3 and is big enough to hold six fluorine atoms as can be seen in the molecule SF₆, while the second period of an element like nitrogen may not be big to comprise 6 fluorine atoms.  

The existence of unoccupied d orbitals are accessible for bonding for period 3 elements and beyond, the size plays a prime function than the tendency to produce more bonds. Hence, the suggestion of the second friend is correct.  


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A student reacts 20.0 mL of 0.248 M H2SO4 with 15.0 mL of 0.195 M NaOH. Write a balanced chemical equation to show this reaction
Molodets [167]

<u>Answer:</u> The concentration of salt (sodium sulfate), sulfuric acid and NaOH in the solution is 0.0418 M, 0.0999 M and 0 M respectively.

<u>Explanation:</u>

To calculate the number of moles for given molarity, we use the equation:

\text{Molarity of the solution}=\frac{\text{Moles of solute}}{\text{Volume of solution (in L)}}     .....(1)

<u>For NaOH:</u>

Initial molarity of NaOH solution = 0.195 M

Volume of solution = 15.0 mL = 0.015 L   (Conversion factor:   1 L = 1000 mL)

Putting values in equation 1, we get:

0.195M=\frac{\text{Moles of NaOH}}{0.015L}\\\\\text{Moles of NaOH}=(0.195mol/L\times 0.015L)=2.925\times 10^{-3}mol

<u>For sulfuric acid:</u>

Initial molarity of sulfuric acid solution = 0.248 M

Volume of solution = 20.0 mL = 0.020 L

Putting values in equation 1, we get:

0.248M=\frac{\text{Moles of }H_2SO_4}{0.020L}\\\\\text{Moles of }H_2SO_4=(0.248mol/L\times 0.020L)=4.96\times 10^{-3}mol

The chemical equation for the reaction of NaOH and sulfuric acid follows:

2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O

By Stoichiometry of the reaction:

2 moles of NaOH reacts with 1 mole of sulfuric acid

So, 2.925\times 10^{-3} moles of KOH will react with = \frac{1}{2}\times 2.925\times 10^{-3}=1.462\times 10^{-3}mol of sulfuric acid

As, given amount of sulfuric acid is more than the required amount. So, it is considered as an excess reagent.

Thus, NaOH is considered as a limiting reagent because it limits the formation of product.

Excess moles of sulfuric acid = (4.96-1.462)\times 10^{-3}=3.498\times 10^{-3}mol

By Stoichiometry of the reaction:

2 moles of KOH produces 1 mole of sodium sulfate

So, 2.925\times 10^{-3} moles of KOH will produce = \frac{1}{2}\times 2.925\times 10^{-3}=1.462\times 10^{-3}mol of sodium sulfate

  • <u>For sodium sulfate:</u>

Moles of sodium sulfate = 1.462\times 10^{-3}moles

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

\text{Molarity of sodium sulfate}=\frac{1.462\times 10^{-3}}{0.035}=0.0418M

  • <u>For sulfuric acid:</u>

Moles of excess sulfuric acid = 3.498\times 10^{-3}mol

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

\text{Molarity of sulfuric acid}=\frac{3.498\times 10^{-3}}{0.035}=0.0999M

  • <u>For NaOH:</u>

Moles of NaOH remained = 0 moles

Volume of solution = [15.0 + 20.0] = 35.0 mL = 0.035 L

Putting values in equation 1, we get:

\text{Molarity of NaOH}=\frac{0}{0.050}=0M

Hence, the concentration of salt (sodium sulfate), sulfuric acid and NaOH in the solution is 0.0418 M, 0.0999 M and 0 M respectively.

8 0
3 years ago
3. Which of the following is not true for atoms? (4 points) They combine to form elements and molecules. They contain negatively
Taya2010 [7]
<h3><u>Answer;</u></h3>

They are made up of elements.

<h3><u>Explanation;</u></h3>
  • An atom is the smallest particle of matter that still retains the property of the element.
  • Two or more atoms combine to form elements or compounds. Elements are formed by two or more similar atoms, while compounds are formed by two or more different elements.
  • Atoms are made up of subatomic particles; protons, electrons and neutrons. Electrons are negatively charged, protons are positively charged while neutrons have no charge.
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Most protein enzymes catalyze only one specific chemical reaction effectively. What feature of protein structure is most directl
babunello [35]

Answer;

d. the specific geometry and types of amino acids in the active site

Explanation;

-Enzymes are highly selective catalysts, meaning that each enzyme only speeds up a specific reaction. The molecules that an enzyme works with are called substrates. The substrates bind to a region on the enzyme called the active site.

-For a substrate to bind to the active site of an enzyme it must fit in the active site and be chemically attracted to it. The shape of an enzyme determines how it works. Enzymes have active sites that substrate molecules (the substances involved in the chemical reaction) fit into when a reaction happens.

8 0
4 years ago
Arrange the three common unit cells in order from least dense to most dense packing. a. face-centered cubic &lt; body-centered c
maks197457 [2]

Answer:

b. primitive cubic < body-centered cubic < face-centered cubic  

Explanation:

The coordination number is defined as <em>the number of atoms (or ions) surrounding an atom (or ion) in a crystal lattice</em>. Its value gives us a measure of how tightly the spheres are packed together. The larger the coordination number, the closer the spheres are to each other.

  • In the <u>primitive cubic</u>, each sphere is in contact with 6 spheres, so its <u>coordination number is 6</u>.
  • In the <u>body-centered cubic</u>, each sphere is in contact with 8 spheres, so its <u>coordination number is 12</u>.
  • In the <u>face-centered cubic</u>, each sphere is in contact with 12 spheres, so its <u>coordination number is 12</u>.

Therefore, the increasing order in density is the primitive cubic first, then the body-centered cubic, and finally the face-centered cubic.

3 0
3 years ago
When the mixture was moved from room temperature to a higher temperature, the mixture turned darker brown. Which of the followin
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Answer:

The equilibrium between the two forms of the gas is disturbed at high temperatures.

7 0
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