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butalik [34]
3 years ago
12

For elements in the third row of the periodic table and beyond, the octet rule is often not obeyed. a friend of yours says this

is because these heavier elements are more likely to make double or triple bonds. another friend of yours says that this is because the heavier elements are larger and can make bonds to more than four atoms at a time. part a which friend is most correct?
Chemistry
1 answer:
Rom4ik [11]3 years ago
4 0

The reason that some of the elements of period three and beyond are steady in spite of not sticking to the octet rule is due to the fact of possessing the tendency of forming large size, and a tendency of making more than four bonds. For example, sulfur, it belongs to period 3 and is big enough to hold six fluorine atoms as can be seen in the molecule SF₆, while the second period of an element like nitrogen may not be big to comprise 6 fluorine atoms.  

The existence of unoccupied d orbitals are accessible for bonding for period 3 elements and beyond, the size plays a prime function than the tendency to produce more bonds. Hence, the suggestion of the second friend is correct.  


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An iron block of mass 18 kg is heated from 285 K to 318 K. If 267.3 kJ is required, what is the specific heat of iron? A. 450.00
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Answer:

  • <u>Option A. 450.00</u>

Explanation:

<u>1) Data:</u>

a) m = 18 kg

b) T₁ = 285 K

c) T₂ = 318 K

d) Q = 267.3 kJ

e) S = ?

<u>2) Principles and equations</u>

The specific heat of a substance is the amount of heat energy absorbed to increase the temperature of certain amount (gram, kg, or moles, depending on the definition or units) of the substance in 1 ° C or 1 K.

The mathematical relation between the specific heat and the heat energy absorbed is:

  • Q = m × S × ΔT

Where,

  • Q is the heat absorbed,
  • S is the specific heat, and
  • ΔT is the temperature increase (T₂ - T₁)

<u>3) Solution:</u>

<u>a) Substitute the data into the equation:</u>

  • 267.3 kJ = 18 kg × S × (318 K - 285 K)

<u>b) Solve for S and compute:</u>

  • S = 267.3 kJ / (18 kg × 33 K) = 0.45 kJ / (Kg . K)

The options have not units, but I notice that the first answer is 1,000 times the answer I obtained, so I will make a conversion of units.

<u>c) Convert to J /( kg . k):</u>

  • 0.45 kJ / (Kg . K) × 1,000 J / kJ = 450 J / (kg . K)

Now we can see that the option A is is the answer, assuming the units.

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2 years ago
A mixture of gases containing 0.20 mol of SO2 and 0.20 mol of O2 in a 4.0 L flask reacts to form SO3. If the temperature is 25ºC
diamong [38]

Answer : The pressure in the flask after reaction complete is, 2.4 atm

Explanation :

To calculate the pressure in the flask after reaction is complete we are using ideal gas equation.

PV=n_TRT\\\\P=(n_1+n_2)\times \frac{RT}{V}

where,

P = final pressure in the flask = ?

R = gas constant = 0.0821 L.atm/mol.K

T = temperature = 25^oC=273+25=298K

V = volume = 4.0 L

n_1 = moles of SO_2 = 0.20 mol

n_2 = moles of O_2 = 0.20 mol

Now put all the given values in the above expression, we get:

P=(0.20+0.20)mol\times \frac{(0.0821L.atm/mol.K)\times (298K)}{4.0L}

P=2.4atm

Thus, the pressure in the flask after reaction complete is, 2.4 atm

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