Answer: 26.5 mm Hg
Explanation:
The vapor pressure is determined by Clausius Clapeyron equation:
where,
= initial pressure at 
= ?
= final pressure at 
= 100 mm Hg
= enthalpy of vaporisation = 28.0 kJ/mol =28000 J/mol
R = gas constant = 8.314 J/mole.K
= initial temperature = 
= final temperature =
Now put all the given values in this formula, we get
![\log (\frac{P_1}{100})=\frac{28000}{2.303\times 8.314J/mole.K}[\frac{1}{299.5}-\frac{1}{267.9}]](https://tex.z-dn.net/?f=%5Clog%20%28%5Cfrac%7BP_1%7D%7B100%7D%29%3D%5Cfrac%7B28000%7D%7B2.303%5Ctimes%208.314J%2Fmole.K%7D%5B%5Cfrac%7B1%7D%7B299.5%7D-%5Cfrac%7B1%7D%7B267.9%7D%5D)
Thus the vapor pressure of 
in mmHg at 26.5 ∘C is 26.5
a. 34 mL; b. 110 mL
a. A tablet containing 150 Mg(OH)₂
Mg(OH)₂ + 2HCl ⟶ MgCl₂ + 2H₂O
<em>Moles of Mg(OH)₂</em> = 150 mg Mg(OH)₂ × [1 mmol Mg(OH)₂/58.32 mg Mg(OH)₂
= 2.572 mmol Mg(OH)₂
<em>Moles of HCl</em> = 2.572 mmol Mg(OH)₂ × [2 mmol HCl/1 mmol Mg(OH)₂]
= 5.144 mmol HCl
Volume of HCl = 5.144 mmol HCl × (1 mmol HCl/0.15 mmol HCl) = 34 mL HCl
b. A tablet containing 850 mg CaCO₃
CaCO₃ + 2HCl ⟶ CaCl₂ + CO₂ + H₂O
<em>Moles of CaCO₃</em> = 850 mg CaCO₃ × [1 mmol CaCO₃/100.09 mg CaCO₃
= 8.492 mmol CaCO₃
<em>Moles of HCl</em> = 8.492 mmol CaCO₃ × [2 mmol HCl/1 mmol CaCO₃]
= 16.98 mmol HCl
Volume of HCl = 16.98 mmol HCl × (1 mL HCl/0.15 mmol HCl) = 110 mL HCl
Answer:
H_2O + 2CrO_4^2- + 3SO_3^2- -> 3SO_3^2- + 2CrO_2^- + 2OH^-
Explanation:
Reduction half reaction
2H_2O + CrO_4^2- + 3e -> CrO_2^- + 4OH^-
Oxidation half reaction
2OH^- + SO_3^2- -> SO_4^2- + H_2O + 2e
Balanced overall equation
H_2O + 2CrO_4^2- + 3SO_3^2- -> 3SO_3^2- + 2CrO_2^- + 2OH^-
