<u><em>I believe the answer you are looking for is position 4 </em></u>, because the northern face of the hemisphere is facing away from the sun not getting
to much heat nor daylight therefore its cold making it winter fully in option 4.
Just a tip option 3 looks like its facing back but half of it is still shown to the sun.
Answer:
MOLAR MASS = 32 g/mol
Explanation:
Condition of standard temperature and pressure(STP) are as follow:
Temperature = 273 K
Pressure = 1 atm (or 100000 Pa)
Here atm is atmosphere and Pa is Pascal
STP conditions arte used for measuring gas density and volume using Ideal Gas Law.Here 1 mole of ideal gas occupies 22.4 L of volume.
According toi Ideal Gas Equation :
PV = nRT
where P = pressure, n= number of moles, V = volume ,R= Ideal Gas Constant and T= temperature

From question:
V=280 ml = 0.28 L
P = 1 atm
R=0.08205 L atm/K mol
T=273 K
Putting values in above formula :

n = 0.0125 moles
Now 

given mass = 0.4 g (given)

On solving we get:
Molar mass = 32 g/mol
Exothermic processes: Making ice cubes,formation of snow in clouds
Endothermic processe: Melting ice cubes, evaporation of water