Answer:
Less
Explanation:
Since [Cu(NH3)4]2+ and [Cu(H2O)6]2+ are Octahedral Complexes the transitions between d-levels explain the majority of the absorbances seen in those chemical compounds. The difference in energy between d-levels is known as ΔOh (ligand-field splitting parameter) and it depends on several factors:
- The nature of the ligand: A spectrochemical series is a list of ligands ordered on ligand strength. With a higher strength the ΔOh will be higher and thus it requires a higher energy light to make the transition.
- The oxidation state of the metal: Higher oxidation states will strength the ΔOh because of the higher electrostatic attraction between the metal and the ligand
A partial spectrochemical series listing of ligands from small Δ to large Δ:
I− < Br− < S2− < Cl− < N3− < F−< NCO− < OH− < C2O42− < H2O < CH3CN < NH3 < NO2− < PPh3 < CN− < CO
Then NH3 makes the ΔOh higher and it requires a higher energy light to make the transition, which means a shorter wavelength.
Answer:
2-ethoxy-2-methylpropan-1-ol
Explanation:
On this reaction, we have an "<u>epoxide"</u> (2-methyl-1,2-epoxypropane). Additionally, we have <u>acid medium</u> (due to the sulfuric acid 
). The acid medium will produce the <u>hydronium ion</u> (
). This ion would be attacked by the oxygen of the epoxide. Then a <u>carbocation</u> would be produced, in this case, the most stable carbocation is the <u>tertiary one</u>. Then an <u>ethanol</u> molecule acts as a nucleophile and will attack the carbocation. Finally, a <u>deprotonation </u>step takes place to produce <u>2-ethoxy-2-methylpropan-1-ol</u>.
See figure 1
I hope it helps!
Answer:
The heat of reaction when hydrogen and oxygen combine to form water is :
<u>C. 571.6 kJ</u>
Explanation:
Enthalpy Change = The enthalpy change for the formation of 1 mole of the substance from their standard state is called the enthalpy of formation.
This is intensive quantity as it is fixed for 1 mole .
Intensive properties = Those properties which are independent on the amount of the substance are intensive properties.
The value of these quantities does not get halve if you divide the substance into two equal parts. example , density, refractive index.
However , the enthalpy of reaction is extensive. Because on increasing the amount the value of the enthalpy also get doubles
Hence for this reaction :
Its value is -285.8 kJ for 1 mole
And here two moles are present . so the value of molar enthalpy is:
-285.8 x 2 = -571.6 kJ
Answer:
The yeast present contains an enzyme called catalase which catalyses the reaction. More the amount of the catalyst added, faster will be the decomposition of the hydrogen peroxide.
Out of the options, glass is the least fluid. The proof of this also lies in the fact that glass is the most difficult to melt out of all of the mentioned substances, and melting point gives us a rough estimate of the strength of intermolecular forces.
