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Electrons transition between energy levels in an atom due to gain or loss of energy. An electron may gain energy and move from its ground state to one of the accessible excited states. The electron quickly returns to ground state, emitting the energy previously absorbed as a photon of light. The wavelength of light emitted is measured using powerful spectrometers.
Atoms can be excited thermally or by irradiation with light of appropriate frequency.
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In chemistry, orbital hybridisation (or hybridization) is the concept of mixing atomic orbitals into new hybrid orbitals (with different energies, shapes, etc., than the component atomic orbitals) suitable for the pairing of electrons to form chemical bonds in valence bond theory.
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