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Answer:
pH = 2.69
Explanation:
The complete question is:<em> An analytical chemist is titrating 182.2 mL of a 1.200 M solution of nitrous acid (HNO2) with a solution of 0.8400 M KOH. The pKa of nitrous acid is 3.35. Calculate the pH of the acid solution after the chemist has added 46.44 mL of the KOH solution to it.</em>
<em />
The reaction of HNO₂ with KOH is:
HNO₂ + KOH → NO₂⁻ + H₂O + K⁺
Moles of HNO₂ and KOH that react are:
HNO₂ = 0.1822L × (1.200mol / L) = <em>0.21864 moles HNO₂</em>
KOH = 0.04644L × (0.8400mol / L) = <em>0.0390 moles KOH</em>
That means after the reaction, moles of HNO₂ and NO₂⁻ after the reaction are:
NO₂⁻ = 0.03900 moles KOH = moles NO₂⁻
HNO₂ = 0.21864 moles HNO₂ - 0.03900 moles = 0.17964 moles HNO₂
It is possible to find the pH of this buffer (<em>Mixture of a weak acid, HNO₂ with the conjugate base, NO₂⁻), </em>using H-H equation for this system:
pH = pKa + log₁₀ [NO₂⁻] / [HNO₂]
pH = 3.35 + log₁₀ [0.03900mol] / [0.17964mol]
<h3>pH = 2.69</h3>
The freezing point of a solution containing 5. 0 grams of KCl and 550.0 grams of water is - 0.45°C
Using the equation,
Δ
= i
m
where:
Δ = change in freezing point (unknown)
i = Van't Hoff factor
= freezing point depression constant
m = molal concentration of the solution
Molality is expressed as the number of moles of the solute per kilogram of the solvent.
Molal concentration is as follows;
MM KCl = 74.55 g/mol
molal concentration = 
molal concentration = 0.1219m
Now, putting in the values to the equtaion Δ = im we get,
Δ = 2 × 1.86 × 0.1219
Δ = 0.4536°C
So, Δ of solution is,
Δ
= 0.00°C - 0.45°C
Δ = - 0.45°C
Therefore,freezing point of a solution containing 5. 0 grams of KCl and 550.0 grams of water is - 0.45°C
Learn more about freezing point here;
brainly.com/question/3121416
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